Institut de Chimie Moléculaire et des Matériaux d'Orsay

Catalyst-Controlled Intermolecular Homobenzylic C(sp3)–H Amination for the Synthesis of β-Arylethylamines. E. Brunard, V. Boquet, T. Saget, E. D. Sosa Carrizo, M. Sircoglou, P. Dauban, J. Am. Chem. Soc., 2024, 146, 5843-5854

Second Coordination Sphere Effect Shifts CO2 to CO Reduction by Iron Porphyrin from Fe0 to FeI. S. Amanullah, P. Gotico, M. Sircoglou, W. Leibl, M. J. Llansola-Portoles, T. Tibiletti, A. Quaranta, Z. Halime, A. Aukauloo, Angewandte Chemie International Edition, 2024, 63, e202314439

Rhodium(II)-Catalyzed Selective C(sp3)−H Amination of Alkanes. V. Boquet, J. A. Guimaraes Naves, E. Brunard, A. Nasrallah, M. Joigneaux, E. D. Sosa Carrizo, T. Saget, B. Darses, M. Sircoglou, P. Dauban, European Journal of Organic Chemistry, 2023, 26, e202300352

Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation. S. Monticelli, A. Talbot, P. Gotico, F. Caillé, O. Loreau, A. Del Vecchio, A. Malandain, A. Sallustrau, W. Leibl, A. Aukauloo, F. Taran, Z. Halime, D. Audisio, Nature Communications, 2023, 14, 4451

Bimetallic Molecular Catalyst Design for Carbon Dioxide Reduction. P. Gotico, Z. Halime, W. Leibl, A. Aukauloo, ChemPlusChem, 2023, 88, e202300222

Divergent Behavior in the Chemistry of Metal-Bis(dithiolene) Complexes Appended with Peripheral Aliphatic Butyl Chains. E. Prignot, C. Zhang, O. Jeannin, Z. Halime, R. Gramage-Doria, F. Camerel, European Journal of Inorganic Chemistry, 2023, 26, e202200591

Efficient Hydrogen Production at pH 7 in Water with a Heterogeneous Electrocatalyst Based on a Neutral Dimeric Cobalt-Dithiolene Complex. C. Zhang, E. Prignot, O. Jeannin, A. Vacher, D. Dragoe, F. Camerel, Z. Halime, R. Gramage-Doria, ACS Catal., 2023, 13, 2367-2373

Bio-Inspired Bimetallic Cooperativity Through a Hydrogen Bonding Spacer in CO2 Reduction. C. Zhang, P. Gotico, R. Guillot, D. Dragoe, W. Leibl, Z. Halime, A. Aukauloo, Angewandte Chemie International Edition, 2023, 62, e202214665

Photocatalytic generation of a non-heme Fe(iii)-hydroperoxo species with O2 in water for the oxygen atom transfer reaction. E. Pugliese, N. T. Vo, A. Boussac, F. Banse, Y. Mekmouche, J. Simaan, T. Tron, P. Gotico, M. Sircoglou, Z. Halime, W. Leibl, A. Aukauloo, Chem. Sci., 2022, 13, 12332-12339

Photocatalytic Hydrogen Production and Carbon Dioxide Reduction Catalyzed by an Artificial Cobalt Hemoprotein. G. A. O. Udry, L. Tiessler-Sala, E. Pugliese, A. Urvoas, Z. Halime, J.-D. Maréchal, J.-P. Mahy, R. Ricoux, Int. J. Mol. Sci., 2022, 23, 14640

Rhodium(II)-Catalyzed Enantioselective Intermolecular Aziridination of Alkenes. V. Boquet, A. Nasrallah, A. L. Dana, E. Brunard, P. H. Di Chenna, F. J. Duran, P. Retailleau, B. Darses, M. Sircoglou, P. Dauban, J. Am. Chem. Soc., 2022, 144, 17156-17164

Dissection of Light-Induced Charge Accumulation at a Highly Active Iron Porphyrin: Insights in the Photocatalytic CO2 Reduction. E. Pugliese, P. Gotico, I. Wehrung, B. Boitrel, A. Quaranta, M.-H. Ha-Thi, T. Pino, M. Sircoglou, W. Leibl, Z. Halime, A. Aukauloo, Angewandte Chemie International Edition, 2022, 61, e202117530

Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad. P. Gotico, C. Herrero, S. Protti, A. Quaranta, S. Sheth, R. Fallahpour, R. Farran, Z. Halime, M. Sircoglou, A. Aukauloo, W. Leibl, Photochemical & Photobiological Sciences, 2022, 21, 247-259

Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction. P. Gotico, W. Leibl, Z. Halime, A. Aukauloo, ChemElectroChem, 2021, 8, 3472-3481

Intercepting a transient non-hemic pyridine N-oxide Fe(iii) species involved in OAT reactions. N. T. Vo, C. Herrero, R. Guillot, T. Inceoglu, W. Leibl, M. Clémancey, P. Dubourdeaux, G. Blondin, A. Aukauloo, M. Sircoglou, Chem. Commun., 2021, 57, 12836-12839

Imbroglio at a photoredox-iron-porphyrin catalyst dyad for the photocatalytic CO2 reduction. A. Trapali, P. Gotico, C. Herrero, M.-H. Ha-Thi, T. Pino, W. Leibl, G. Charalambidis, C. Athanassios, Z. Halime, A. Aukauloo, Comptes Rendus Chimie, 2021, 1-14

Second-sphere hydrogen-bonding enhances heterogeneous electrocatalytic CO2 to CO reduction by iron porphyrins in water. C. Zhang, D. Dragoe, F. Brisset, B. Boitrel, B. Lassalle-Kaiser, W. Leibl, Z. Halime, A. Aukauloo, Green Chem., 2021, 23, 8979-8987

Tracking Charge Accumulation in a Functional Triazole-Linked Ruthenium-Rhenium Dyad Towards Photocatalytic Carbon Dioxide Reduction. P. Gotico, T.-T. Tran, A. Baron, B. Vauzeilles, C. Lefumeux, M.-H. Ha-Thi, T. Pino, Z. Halime, A. Quaranta, W. Leibl, A. Aukauloo, ChemPhotoChem, 2021, 5, 654-664

Enhanced Photoinduced Electron Transfer Through a Tyrosine Relay in a De Novo Designed Protein Scaffold Bearing a Photoredox Unit and a FeIIS4 Site. A. Tebo, A. Quaranta, V. L. Pecoraro, A. Aukauloo, ChemPhotoChem, 2021, 5, 665-668

Ligand Radical Mediated Water Oxidation by a Family of Copper o-Phenylene Bis-oxamidate Complexes. S. Chattopadhyay, A. Ghatak, Y. Ro, R. Guillot, Z. Halime, A. Aukauloo, A. Dey, Inorg. Chem., 2021, 60, 9442-9455

Tracking light-induced electron transfer toward O2 in a hybrid photoredox-laccase system. R. Farran, Y. Mekmouche, N. T. Vo, C. Herrero, A. Quaranta, M. Sircoglou, F. Banse, P. Rousselot-Pailley, A. J. Simaan, A. Aukauloo, T. Tron, W. Leibl, iScience, 2021, 24, 102378

Phthalocyanine as a Bioinspired Model for Chlorophyll f-Containing Photosystem II Drives Photosynthesis into the Far-Red Region. J. Follana-Berná, R. Farran, W. Leibl, A. Quaranta, Á. Sastre-Santos, A. Aukauloo, Angewandte Chemie International Edition, 2021, 60, 12284-12288

Through-Space Electrostatic Interactions Surpass Classical Through-Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins. A. Khadhraoui, P. Gotico, W. Leibl, Z. Halime, A. Aukauloo, ChemSusChem, 2021, 14, 1308-1315

Efficient light activation of a [Ru(bpy)(tpy)Cl]+ catalyst by a porphyrin photosensitizer at small driving force. G. Charalambidis, A. Charisiadis, S. Margiola, A. Coutsolelos, A. Aukauloo, W. Leibl, A. Quaranta, Polyhedron, 2020, 190, 114775

Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures. P. Gotico, Z. Halime, A. Aukauloo, Dalton Trans., 2020, 49, 2381-2396

Atropisomeric Hydrogen Bonding Control for CO2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins. P. Gotico, L. Roupnel, R. Guillot, M. Sircoglou, W. Leibl, Z. Halime, A. Aukauloo, Angewandte Chemie International Edition, 2020, 59, 22451-22455

Visible light-driven simultaneous water oxidation and quinone reduction by a nano-structured conjugated polymer without co-catalysts. J. Patel, X. Yuan, S. M. Marinho, W. Leibl, H. Remita, A. Aukauloo, Chem. Sci., 2020

Spectroscopic Characterisation of a Bio-Inspired Ni-Based Proton Reduction Catalyst Bearing a Pentadentate N2S3 Ligand with Improved Photocatalytic Activity. P. Gotico, D. Moonshiram, C. Liu, X. Zhang, R. Guillot, A. Quaranta, Z. Halime, W. Leibl, A. Aukauloo, Chemistry – A European Journal, 2020, 26, 2859 – 2868

Time-resolved X-ray absorption spectroelectrochemistry of redox active species in solution. K. Cheaib, B. Maurice, T. Mateo, Z. Halime, B. Lassalle-Kaiser, Journal of Synchrotron Radiation, 2019, 26, 1980-1985

A Reversible Electron Relay to Exclude Sacrificial Electron Donors in the Photocatalytic Oxygen Atom Transfer Reaction with O2 in Water. N. T. Vo, Y. Mekmouche, T. Tron, R. Guillot, F. Banse, Z. Halime, M. Sircoglou, W. Leibl, A. Aukauloo, Angewandte Chemie International Edition, 2019, 58, 16023-16027

Electronic and spin delocalization in a switchable trinuclear triphenylene trisemiquinone bridged Ni3 complex. Y. Wang, F. Lambert, E. Rivière, R. Guillot, C. Herrero, A. Tissot, Z. Halime, T. Mallah, Chem. Commun., 2019, 55, 12336-12339

Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins. P. Gotico, B. Boitrel, R. Guillot, M. Sircoglou, A. Quaranta, Z. Halime, W. Leibl, A. Aukauloo, Angewandte Chemie International Edition, 2019, 58, 4504-4509

Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water. A. Khadhraoui, P. Gotico, B. Boitrel, W. Leibl, Z. Halime, A. Aukauloo, Chem. Commun., 2018, 54, 11630-11633

Visible Light-Driven Reduction of CO2 to CO and Its Subsequent Valorization in Carbonylation Chemistry and 13C Isotope Labelling. P. Gotico, A. Del Vecchio, D. Audisio, A. Quaranta, Z. Halime, W. Leibl, A. Aukauloo, ChemPhotoChem, 2018, 2, 715-719

Water Molecules Gating a Photoinduced One Electron Two Protons Transfer in a Tyr/His model of Photosystem II. G. Chararalambidis, S. Das, A. Trapali, A. Quaranta, M. Orio, Z. Halime, P. Fertey, R. Guillot, C. Athanassios, W. Leibl, A. Aukauloo, M. Sircoglou, Angew. Chem. Int. Ed., 2018, 57, 9013-9017

Snapshots of Light Induced Accumulation of Two Charges on Methylviologen using a Sequential Nanosecond Pump–Pump Photoexcitation. T.-T. Tran, M.-H. Ha-Thi, T. Pino, A. Quaranta, C. Lefumeux, W. Leibl, A. Aukauloo, J. Phys. Chem. Lett., 2018, 9, 1086-1091

Light-Induced Activation of the Du Bois [RhII2(Esp)2] Catalyst for Nitrogen Atom Transfer Reactions. R. Farran, C. Ducloiset, J. Buendia, N. T. Vo, R. Guillot, Z. Halime, P. Dauban, W. Leibl, M. Sircoglou, A. Aukauloo, ChemPhotoChem, 2017, 1, 562-567

Time-Resolved Interception of Multiple-Charge Accumulation in a Sensitizer–Acceptor Dyad. S. Mendes marinho, M.-H. Ha-Thi, V.-T. Pham, A. Quaranta, T. Pino, C. Lefumeux, T. Chamaillé, W. Leibl, A. Aukauloo, Angewandte Chemie International Edition, 2017, 11, 15936–15940

Intramolecular Photogeneration of a Tyrosine Radical in a Designed Protein. A. G. Tebo, A. Quaranta, C. Herrero, V. L. Pecoraro, A. Aukauloo, ChemPhotoChem, 2017, 1, 89-92

Light-driven electron transfer in a modular assembly of a ruthenium(II) polypyridine sensitiser and a manganese(II) terpyridine unit separated by a redox active linkage. DFT analysis. A. G. Tebo, S. Das, R. Farran, C. Herrero, A. Quaranta, R. Fallahpour, S. Protti, M.-F. Charlot, A. Aukauloo, W. Leibl, Comptes Rendus Chimie, 2017, 20, 323-332

Elucidating the light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved x-ray absorption spectroscopy. D. Moonshiram, A. Picon, Á. Vázquez-Mayagoitia, X. Zhang, M.-F. Tu, P. Garrido-Barros, J.-P. Mahy, F. Avenier, A. Aukauloo, Chem. Commun., 2017, 53, 2725-2728

Monoanionic Dipyrrin–Pyridine Ligands: Synthesis, Structure and Photophysical Properties. C. Ducloiset, P. Jouin, E. Paredes, R. Guillot, M. Sircoglou, M. Orio, W. Leibl, A. Aukauloo, European Journal of Inorganic Chemistry, 2015, 2015, 5405-5410

Visible-Light-Driven Oxidation of Organic Substrates with Dioxygen Mediated by a [Ru(bpy)3]2+/Laccase System. L. Schneider, Y. Mekmouche, P. Rousselot-Pailley, A. J. Simaan, V. Robert, M. Réglier, A. Aukauloo, T. Tron, ChemSusChem, 2015, 8, 3048-3051

Redox Noninnocence of the Bridge in Copper(II) Salophen and Bis(oxamato) Complexes. D. De Bellefeuille, M. Orio, A.-L. Barra, A. Aukauloo, Y. Journaux, C. Philouze, X. Ottenwaelder, F. Thomas, Inorg. Chem., 2015, 54, 9013-9026

Synergistic "ping-pong" energy transfer for efficient light activation in a chromophore-catalyst dyad. A. Quaranta, G. Charalambidis, C. Herrero, S. Margiola, W. Leibl, A. Coutsolelos, A. Aukauloo, Phys. Chem. Chem. Phys., 2015, 17, 24166-24172

Ingénierie de la photosynthese artificielle. J.-F. Cornet, A. Aukauloo, F. Gloaguen, W. Leibl, L'actualité chimique, 2015, 397-398, 69-74

Successive light-induced two electron transfers in a Ru-Fe supramolecular assembly: from Ru-Fe(ii)-OH2 to Ru-Fe(iv)-oxo. C. Herrero, A. Quaranta, M. Sircoglou, K. Senechal-David, A. Baron, I. M. Marin, C. Buron, J.-P. Baltaze, W. Leibl, A. Aukauloo, F. Banse, Chem. Sci., 2015, 6, 2323-2327

Carbon dioxide reduction via light activation of a ruthenium-Ni(cyclam) complex. C. Herrero, A. Quaranta, S. El Ghachtouli, B. Vauzeilles, W. Leibl, A. Aukauloo, Physical Chemistry Chemical Physics, 2014, 16, 12067-12072

Intramolecular photoinduced electron transfer in cobalt(II) chlathrochelate-zinc porphyrin assemblies leading to long-lived Co(I) species. S. El Ghachtouli, R. Guillot, W. Leibl, A. Aukauloo, Journal of Porphyrins and Phthalocyanines, 2014, 18, 1125-1130

A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production. S. Cherdo, S. E. Ghachtouli, M. Sircoglou, F. Brisset, M. Orio, A. Aukauloo, Chemical Communications, 2014, 50, 13514-13516

Electrochemical Implication of a Hydrogen-Bonded Imidazole on a Redox-Active-Bound Phenolate Group. S. El Ghachtouli, B. Lassalle-Kaiser, R. Guillot, A. Aukauloo, European Journal of Inorganic Chemistry, 2014, 2014, 4750-4755

Ruthenium-based molecular compounds for oxygen evolution in acidic media. N. Mbemba, C. Herrero, A. Ranjbari, A. Aukauloo, S.-A. Grigoriev, P. Millet, Int. J. Hydrogen Energy, 2013, 38, 8590-8596

Copper Salts as Additives in Gold(I)-Catalyzed Reactions. A. Guérinot, W. Fang, M. Sircoglou, C. Bour, S. Bezzenine-Lafollée, V. Gandon, Angewandte Chemie International Edition, 2013, 52, 5848-5852

Monometallic Cobalt–Trisglyoximato Complexes as Precatalysts for Catalytic H2 Evolution in Water. S. E. Ghachtouli, M. Fournier, S. Cherdo, R. Guillot, M.-F. Charlot, E. Anxolabéhère-Mallart, M. Robert, A. Aukauloo, The Journal of Physical Chemistry C, 2013, 117, 17073-17077

Identification of the Different Mechanisms of Activation of a [RuII(tpy)(bpy)(OH2)]2+ Catalyst by Modified Ruthenium Sensitizers in Supramolecular Complexes. C. Herrero, A. Quaranta, R.-A. Fallahpour, W. Leibl, A. Aukauloo, The Journal of Physical Chemistry C, 2013, 117, 9605-9612

Light-induced tryptophan radical generation in a click modular assembly of a sensitiser-tryptophan residue. S. Sheth, A. Baron, C. Herrero, B. Vauzeilles, A. Aukauloo, W. Leibl, Photochem. Photobiol. Sci., 2013, 12, 1074-1078

Click Chemistry as a Convenient Tool for the Incorporation of a Ruthenium Chromophore and a Nickel–Salen Monomer into a Visible-Light-Active Assembly. C. Herrero, L. Batchelor, A. Baron, S. El Ghachtouli, S. Sheth, R. Guillot, B. Vauzeilles, M. Sircoglou, T. Mallah, W. Leibl, A. Aukauloo, European Journal of Inorganic Chemistry, 2013, 2013, 494-499

Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen-Atom Transfer. F. Avenier, C. Herrero, W. Leibl, A. Desbois, R. Guillot, J.-P. Mahy, A. Aukauloo, Angew. Chem. Intern. Ed., 2013, 52, 3634-3637

Heterobimetallic Rare Earth–Lithium Complexes with Fewer Than Three Binaphtholates. M. Sircoglou, J. Yang, R. Guillot, S. Bezzenine-Lafollée, V. Gandon, European Journal of Inorganic Chemistry, 2013, 2013, 2807-2811

Cobalt-Based Particles Formed upon Electrocatalytic Hydrogen Production by a Cobalt Pyridine Oxime Complex. S. E. Ghachtouli, R. Guillot, F. Brisset, A. Aukauloo, ChemSusChem, 2013, 6, 2226-2230