Jerome Hannedouche
Jérôme Hannedouche received his PhD degree (2004) from the University of Warwick (UK) under the supervision of Prof. Martin Wills. After a 2-year postdoctoral stay at the Université Catholique de Louvain (Belgium) with Prof. Olivier Riant, he was appointed (2006) at the Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO) (Université Paris-Sud/Université Paris-Saclay, France) as a CNRS fellow researcher. In 2019, he was promoted CNRS Research Director. His research interests lie in the development and mechanistic study of novel synthetic methodologies in asymmetric catalysis, mainly for C–N bond formation via hydroamination reaction catalysed by rare-earth and first-row late transition metal elements.
Well-Defined β-Diketiminatocobalt(II) Complexes for Alkene Cyclohydroamination of Primary Amines. C. Lepori, P. Gómez-Orellana, A. Ouharzoune, R. Guillot, A. Lledós, G. Ujaque, J. Hannedouche, ACS Catalysis, 2018, 4446-4451.
Well-Defined Four-Coordinate Iron(II) Complexes For Intramolecular Hydroamination of Primary Aliphatic Alkenylamines. E. Bernoud, P. Oulié, R. Guillot, M. Mellah, J. Hannedouche, Angew. Chem. Int. Ed., 2014, 53, 4930-4934.
Anti-Markovnikov Hydroamination of Aromatic Alkenes with Secondary Amines Catalyzed by Easily Accessible Yttrium Complexes. S. Germain, E. Schulz, J. Hannedouche, ChemCatChem, 2014, 6, 2065-2073.
Asymmetric Assisted Tandem Catalysis: Hydroamination followed by Asymmetric Friedel–Crafts Reaction from a Single Chiral N,N,N′,N′-Tetradentate Pyridylmethylamine-Based Ligand. A. Aillerie, V. Rodriguez-Ruiz, R. Carlino, F. Bourdreux, R. Guillot, S. Bezzenine-Lafollée, R. Gil, D. Prim, J. Hannedouche, ChemCatChem, 2016, 8, 2455–2460 .
Simple Chiral Diaminobinaphthyl Dilithium Salts for Intramolecular Catalytic Asymmetric Hydroamination of Amino-1,3-dienes. J. Deschamp, C. Olier, E. Schulz, R. Guillot, J. Hannedouche, J. Collin, Adv. Synth. & Catal., 2010, 352, 2171-2176.
Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination. J. Hannedouche, I. Aillaud, J. Collin, E. Schulz, A. Trifonov, Chem. Commun., 2008, 3552-3554.
Iron-Catalyzed Positional and Geometrical Isomerization of Alkenes. A.-H. Obeid, J. Hannedouche, Adv. Synth. Catal., 2023, 365, 1100-1111
Le fer, un métal « précieux » au service d’une réaction à économie d’atomes. A. Stadler, R. Gil, S. Bezzenine, J. Hannedouche, L'Act. Chim., 2022, 473-474, 33-39
Substrate-Dependent Selectivity in Sc(OTf)3-Catalyzed Cyclization of Alkenoic Acids and N-Protected Alkenamides. H. Zhang, R. Carlino, R. Guillot, R. Gil, S. Bezzenine, J. Hannedouche, Catalysts, 2022, 12, 1481
Visible Light Initiated Palladium-catalyzed Cross-couplings by PPh3 Uncaging from Azobenzene Ruthenium-Arene Complex. L. Rocard, J. Hannedouche, N. Bogliotti, Chem. Eur. J., 2022, 28, e202200519
Earth-Abundant 3d Transition Metal Catalysts for Hydroalkoxylation and Hydroamination of Unactivated Alkenes. L. Rocard, D. Chen, A. Stadler, H. Zhang, R. Gil, S. Bezzenine, J. Hannedouche, Catalysts, 2021, 11, 674-710
Alkene Hydroamination via Earth-Abundant Transition Metal (Fe, Co, Cu and Zn) Catalysis: A Mechanistic Overview. P. Colonna, S. Bezzenine, R. Gil, J. Hannedouche, Adv. Synth. Catal, 2020, 362, 1550-1563
Photoredox-initiated 1,2-Difunctionalization of Alkenes with N-Chloro S-Fluoroalkyl Sulfoximines. A. Prieto, P. Diter, M. Toffano, J. Hannedouche, E. Magnier, Adv. Synth. Catal., 2019, 361, 436-440
C1-symmetric β-Diketiminatoiron(II) Complexes for Hydroamination of Primary Alkenylamines. C. Lepori, R. Guillot, J. Hannedouche, Advanced Synthesis & Catalysis, 2019, 361, 714-719
Experimental and computational mechanistic studies of the β-diketiminatoiron(II)-catalysed hydroamination of alkenes tethered to primary amines. C. Lepori, E. Bernoud, R. Guillot, S. Tobisch, J. Hannedouche, Chem. Eur. J., 2019, 25, 835-844
Facile Preparation of Vinyl S-Trifluoromethyl NH Aryl Sulfoximines. A.-L. Barthelemy, A. Prieto, P. Diter, J. Hannedouche, M. Toffano, E. Anselmi, E. Magnier, Eur. J. Org. Chem., 2018, 3764-3770
Well-Defined β-Diketiminatocobalt(II) Complexes for Alkene Cyclohydroamination of Primary Amines. C. Lepori, P. Gómez-Orellana, A. Ouharzoune, R. Guillot, A. Lledós, G. Ujaque, J. Hannedouche, ACS Catal., 2018, 8, 4446-4451
Hydroamination and Hydroaminoalkylation of Alkenes by Group 3–5 Elements: Recent Developments and Comparison with Late Transition Metals. J. Hannedouche, E. Schulz, Organometallics, 2018, 37, 4313-4326
Mechanistic Insights into First-row Late Transition Metal-catalysed (formal) Hydroamination of Unactivated Alkenes. J. Hannedouche, CHIMIA, 2018, 72, 635-641
First-Row Late Transition Metals for Catalytic (Formal) Hydroamination of Unactivated Alkenes. C. Lepori, J. Hannedouche, Synthesis, 2017, 49, 1158-1167
First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation. S. Bezzenine-Lafollée, R. Gil, D. Prim, J. Hannedouche, Molecules, 2017, 22, 1901-1929
Lithium-Catalyzed anti-Markovnikov Intermolecular Hydroamination Reactions of Vinylarenes and Simple Secondary Amines. S. Germain, M. Lecoq, E. Schulz, J. Hannedouche, ChemCatChem, 2017, 9, 1749-1753
Novel yttrium and zirconium catalysts featuring reduced Ar-BIANH2 ligands for olefin hydroamination (Ar-BIANH2 = bis-arylaminoacenaphthylene). A. Cimino, F. Moscatelli, F. Ferretti, F. Ragaini, S. Germain, J. Hannedouche, E. Schulz, L. Luconi, A. Rossin, G. Giambastiani, New J. Chem., 2016, 40, 10285-10293
Asymmetric Assisted Tandem Catalysis: Hydroamination followed by Asymmetric Friedel–Crafts Reaction from a Single Chiral N,N,N′,N′-Tetradentate Pyridylmethylamine-Based Ligand. A. Aillerie, V. Rodriguez-Ruiz, R. Carlino, F. Bourdreux, R. Guillot, S. Bezzenine-Lafollée, R. Gil, D. Prim, J. Hannedouche, ChemCatChem, 2016, 8, 2455–2460
Mixing and matching chiral cobalt- and manganese-based calix-salen catalysts for the asymmetric hydrolytic ring opening of epoxides. H. Dandachi, E. Zaborova, E. Kolodziej, O. R.-P. David, J. Hannedouche, M. Mellah, N. Jaber, E. Schulz, Tetrahedron: Asymmetry, 2016, 27, 246-253
Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes. E. Bernoud, C. Lepori, M. Mellah, E. Schulz, J. Hannedouche, Catal. Sci. Technol., 2015, 5, 2017-2037
Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C-N, C-O and C-P bond. V. Rodriguez-Ruiz, R. Carlino, S. Bezzenine-Lafollee, R. Gil, D. Prim, E. Schulz, J. Hannedouche, Dalton Trans., 2015, 44, 12029-12059
Anti-Markovnikov Hydroamination of Aromatic Alkenes with Secondary Amines Catalyzed by Easily Accessible Yttrium Complexes. S. Germain, E. Schulz, J. Hannedouche, ChemCatChem, 2014, 6, 2065-2073
Well-Defined Four-Coordinate Iron(II) Complexes For Intramolecular Hydroamination of Primary Aliphatic Alkenylamines. E. Bernoud, P. Oulié, R. Guillot, M. Mellah, J. Hannedouche, Angewandte Chemie International Edition, 2014, 53, 4930-4934
Cationic Group-IV pincer-type complexes for polymerization and hydroamination catalysis. L. Luconi, J. Klosin, A. J. Smith, S. Germain, E. Schulz, J. Hannedouche, G. Giambastiani, Dalton Trans., 2013, 42, 16056-16065
Asymmetric Hydroamination: A Survey of the Most Recent Developments. J. Hannedouche, E. Schulz, Chemistry – A European Journal, 2013, 19, 4972-4985
Intramolecular Hydroamination Reactions Catalyzed by Neutral and Cationic Group IV Pyridylamido Complexes. L. Luconi, A. Rossin, G. Tuci, S. Germain, E. Schulz, J. Hannedouche, G. Giambastiani, ChemCatChem, 2013, 5, 1142-1151
LiCl-effect on asymmetric intramolecular hydroamination catalyzed by binaphthylamido yttrium complexes. Y. Chapurina, R. Guillot, D. Lyubov, A. Trifonov, J. Hannedouche, E. Schulz, Dalton Trans., 2013, 42, 507-520
29Si-1H IMPACT HMBC: a suitable tool for analyzing silylated derivatives. J. Farjon, A. Giros, S. Deloisy, L. Blanco, J. Hannedouche, E. Schulz, D. Merlet, Magn. Reson. Chem., 2013, 51, 230-233
Intramolecular enantioselective hydroamination catalyzed by rare earth binaphthylamides. J. Hannedouche, J. Collin, A. Trifonov, E. Schulz, J. Organomet. Chem., 2011, 696, 255-262
Alkyl Complexes of Lanthanum and Samarium Supported by a Chiral Binaphthylamido Ligand. Syntheses, Structures, and Catalytic Activity in Hydroamination of Amino-1,3-dienes. I. Aillaud, C. Olier, Y. Chapurina, J. Collin, E. Schulz, R. Guillot, J. Hannedouche, A. Trifonov, Organometallics, 2011, 30, 3378-3385
Catalytic, Enantioselective Intramolecular Hydroamination of Primary Amines Tethered to Di- and Trisubstituted Alkenes. Y. Chapurina, H. Ibrahim, R. Guillot, E. Kolodziej, J. Collin, A. Trifonov, E. Schulz, J. Hannedouche, J. Org. Chem., 2011, 76, 10163-10172
Comparison of yttrium binaphthylamido alkyl and amide complexes for enantioselective intramolecular hydroamination. I. Aillaud, J. Collin, J. Hannedouche, E. Schulz, A. Trifonov, Tetrahedron Lett., 2010, 51, 4742-4745
Well-defined and easily accessible yttrium complexes for enantioselective cyclisation of amines tethered to 1,2-di-substituted alkenes. Y. Chapurina, J. Hannedouche, J. Collin, R. Guillot, E. Schulz, A. Trifonov, Chem. Commun., 2010, 46, 6918-6920
Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare-Earth Complexes. C. Queffelec, F. Boeda, A. Pouilhès, A. Meddour, C. Kouklovsky, J. Hannedouche, J. Collin, E. Schulz, ChemCatChem, 2010, 3, 122-126
Simple Chiral Diaminobinaphthyl Dilithium Salts for Intramolecular Catalytic Asymmetric Hydroamination of Amino-1,3-dienes. J. Deschamp, C. Olier, E. Schulz, R. Guillot, J. Hannedouche, J. Collin, Adv. Synth. Catal., 2010, 352, 2171-2176