Christophe Bour

Build. 670, office 2218 – LCM – ICMMO - UMR 8182
Université Paris-Saclay
Bâtiment 670
17-19 Avenue des Sciences
91400 Orsay
FRANCE
+33 1 69 15 76 51
christophe.bour@u-psud.fr
https://orcid.org/0000-0001-6733-5284
Education:
June 2000
- Diploma of « DEUG » in science with honors, University Louis Pasteur, Strasbourg
June 2001
- Bachelor of Science in chemistry with honours, University Louis Pasteur, Strasbourg
- 1st year of Magistère de Chimie- Biologie
June 2003
- Master degree in organic and supramolecular chemistry, with honours (ranked 5th), University Louis Pasteur, Strasbourg, Master internship group of Dr. J. Suffert “Cyclocarbopalladation 5-exo-dig and C-H activation”
- Diploma of « Magistère Interdisciplinaire en Chimie-Biologie » with honours, Université Louis Pasteur, Strasbourg
Dec. 2006
- PhD Thesis at the University Louis Pasteur of Strasbourg, (grant from the Ministery of Research), Group of Dr. J. Suffert, “4-exo-dig and 5-exo-dig Cyclocarbopalladation: an expeditive solution towards molecular diversity ?”
Jury: Dr. C. Aubert, Pr. E. Fouquet, Pr. S. Nolan, Pr. P. Pâle, Dr. J. Suffert
Sept. 2015
- Diploma of « Habilitation à Diriger des Recherches », University Paris Sud. “De nouveaux procédés catalytiques pour l’activation carbophile par des acides de Lewis π” Jury: Dr. V. Michelet, Pr. C. Darcel, Pr. S. Bellemin-Laponnaz, Pr. R. Poli
- Authorized to apply to Professor positions (CNU 32th section).
Academic Carrier :
2002
- Master internship “Development of a new insecticide family” ,
SYNGENTA Crop Science, Basel, Switzerland, Dr. Peter Renold
2007-2008
- Postdoctoral fellow “Development of enantioselectives methodologies in gold catalysis”
Institute of Chemical Research of Catalonia, Tarragone, Espagne, Prof. Antonio M. Echavarren
2009-2010
- Postdoctoral fellow “Total Synthesis of Salvinorin A”, ECPM, UMR 7509, Université de Strasbourg, Dr. Gilles Hanquet
Since 1st septembre 2010
- Maître de Conférences, section 32, ICMMO (UMR 8182),
Université Paris Sud, équipe de catalyse moléculaire, Gandon‘s group
Area of expertise
- Homogeneous catalysis
- Organometallic chemistry
- Chemistry of the main group elements
- Organic chemistry
- Late transition metals chemistry
Calcium(II)-Catalyzed Synthesis of Sulfoximinocyclopentenones. X. Chen, C. Bour, E. Kolodziej, R. Guillot, N. S. George, A. Alix, V. Gandon, Advanced Synthesis & Catalysis, 2024, n/a
Aluminum-Catalyzed Intramolecular Vinylation of Arenes by Vinyl Cations. W. Lin, A. Alix, R. Guillot, V. Gandon, C. Bour, Org. Lett., 2024, 26, 3267-3272
Squaramide/Li+-Catalyzed Direct SN1-Type Reaction of Vinyl Triflates with Difluoroenoxysilanes through Vinyl Cations. Y. Chen, V. Gandon, C. Bour, Organic Letters, 2022, 24, 6978-6982
Atroposelective Synthesis of Tetrahydropyrrolo[3,2-c]azepine Derivatives Through Gold(I)-Catalyzed Hydroarylation. Q. Gaignard-Gaillard, X. Han, A. Alix, C. Bour, R. Guillot, V. Gandon, A. Voituriez, Advanced Synthesis & Catalysis, 2022, 364, 4415-4420
A cyclic divalent N(I) species isoelectronic to carbodiphosphoranes. J. Tian, M. Cordier, C. Bour, A. Auffrant, V. Gandon, Chemical Communications, 2022, 58, 5741-5744
Transition structures for the oxy-ene reaction. S. Yang, S. Miaskiewicz, C. Bour, A. Alix, V. Gandon, Chemical Communications, 2022, 58, 4751-4754
Potassium Carbonate to Unlock a GaCl3-Catalyzed C–H Propargylation of Arenes. M. Vayer, S. Rodrigues, S. Miaskiewicz, D. Gatineau, Y. Gimbert, V. Gandon, C. Bour, ACS Catal., 2022, 12, 305-315
Modular Synthesis of 9,10-Dihydroacridines through an ortho-C Alkenylation/Hydroarylation Sequence between Anilines and Aryl Alkynes in Hexafluoroisopropanol. S. Wang, G. Force, J.-F. Carpentier, Y. Sarazin, C. Bour, V. Gandon, D. Lebœuf, Organic Letters, 2021, 23, 2565-2570
DFT Analysis into the Calcium(II)-Catalyzed Coupling of Alcohols With Vinylboronic Acids: Cooperativity of Two Different Lewis Acids and Counterion Effects. S. Yang, C. Bour, D. Lebœuf, V. Gandon, Journal of Organic Chemistry, 2021, 86, 9134-9144
Alkynophilicity of Group 13 MX3 Salts: A Theoretical Study. S. Yang, A. Alix, C. Bour, V. Gandon, Inorganic Chemistry, 2021, 60, 5507-5522
Exploring the Limits of π-Acid Catalysis Using Strongly Electrophilic Main Group Metal Complexes: The Case of Zinc and Aluminium. J. Tian, Y. Chen, M. Vayer, A. Djurovic, R. Guillot, R. Guermazi, S. Dagorne, C. Bour, V. Gandon, Chemistry – A European Journal, 2020, 26, 12831 - 12838
On the Superior Activity of In(I) versus In(III) Cations Toward ortho-C-Alkylation of Anilines and Intramolecular Hydroamination of Alkenes. Z. Li, S. Yang, G. Thiery, V. Gandon, C. Bour, J. Org. Chem., 2020, 85, 12947-12959
Lewis Acid/Hexafluoroisopropanol: A Promoter System for Selective ortho-C-Alkylation of Anilines with Deactivated Styrene Derivatives and Unactivated Alkenes. S. Wang, G. Force, R. Guillot, J.-F. Carpentier, Y. Sarazin, C. Bour, V. Gandon, D. Lebœuf, ACS Catalysis, 2020, 10, 10794-10802
Superelectrophilic Gallium(III) Homodimers in Gallium Chloride-Mediated Methylation of Benzene: A Theoretical Study. S. Yang, C. Bour, V. Gandon, ACS Catalysis, 2020, 10, 3027-3033
Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s. J. Hammoud, F. Abou-Khalil, T. Roisnel, V. Dorcet, C. Bour, V. Gandon, D. Leboeuf, J.-F. Carpentier, Y. Sarazin, Dalton Trans., 2020, 49, 13017-13028
Exploring the Versatility of 7-Alkynylcycloheptatriene Scaffolds Under π-Acid Catalysis. M. Vayer, C. Bour, V. Gandon, European Journal of Organic Chemistry, 2020, n/a, 5350-5357
Bimolecular vinylation of arenes by vinyl cations. Z. Li, V. Gandon, C. Bour, Chem. Commun., 2020, 56, 6507-6510
Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence. S. Wang, R. Guillot, J.-F. Carpentier, Y. Sarazin, C. Bour, V. Gandon, D. Lebœuf, Angewandte Chemie, 2020, 132, 1150-1154
Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence. S. Wang, R. Guillot, J.-F. Carpentier, Y. Sarazin, C. Bour, V. Gandon, D. Leboeuf, Angewandte Chemie International Edition, 2019, 59, 1134-1138
Synthesis of Medium-Sized Carbocycles by Gallium-Catalyzed Tandem Carbonyl-Olefin Metathesis/Transfer Hydrogenation. A. Djurovic, M. Vayer, Z. Li, R. Guillot, J.-P. Baltaze, V. Gandon, C. Bour, Organic Letters, 2019, 21, 8132-8137
Empirical Estimation of the Molecular Weight of Gold Complexes in Solution by Pulsed-Field Gradient NMR. G. Hamdoun, C. Bour, V. Gandon, J.-N. Dumez, Organometallics, 2018, 37, 4692-4698
Gallium-Catalyzed Scriabine Reaction. M. Pareek, C. Bour, V. Gandon, Org. Lett., 2018, 20, 6957-6960
Spatially encoded diffusion-ordered NMR spectroscopy of reaction mixtures in organic solvents. G. Hamdoun, L. Guduff, C. Van Heijenoort, C. Bour, V. Gandon, J.-N. Dumez, Analyst, 2018, 143, 3458-3464
Synthesis of 3-Substituted 3-Bromo-1-phenylallenes from Alkynylcycloheptatrienes. M. Vayer, R. Guillot, C. Bour, V. Gandon, J. Org. Chem., 2018, 83, 11309–11317
Iron-Catalyzed Reductive Ethylation of Imines with Ethanol. M. Vayer, S. P. Morcillo, J. Dupont, V. Gandon, C. Bour, Angewandte Chemie, International Edition, 2018, 57, 3228-3232
Catalytic Use of Low-Valent Cationic Gallium(I) Complexes as π-Acids. Z. Li, G. Thiery, M. R. Lichtenthaler, R. Guillot, I. Krossing, V. Gandon, C. Bour, Advanced Synthesis & Catalysis, 2018, 360, 544-549
Functionalization of Mo132 Keplerate Nanocapsules by Cyclic Carboxylates: L-proline vs Cyclopentanecarboxylate. M. Awada, S. Floquet, M. Haouas, N. Watfa, J. Marrot, C. Roch-Marchal, V. Coeffard, C. Greck, C. Bour, V. Gandon, F. Taulelle, E. Cadot, Current Inorganic Chemistry, 2017, 7, 39-47
Revealing the Activity of pi-Acid Catalysts Using a 7-Alkynyl Cycloheptatriene. V. Gandon, M. Vayer, R. Guillot, C. Bour, Chemistry – A European Journal, 2017, Volume 23, Issue 56, 13901–13905
Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands. B. Michelet, D. Lebœuf, C. Bour, K. Škoch, F. Horký, P. Štěpnička, V. Gandon, ChemPlusChem, 2017, 82, 442-448
Synthesis and Characterizations of Keplerate Nanocapsules Incorporating L- and D-Tartrate Ligands. M. Awada, S. Floquet, J. Marrot, M. Haouas, S. P. Morcillo, C. Bour, V. Gandon, V. Coeffard, C. Greck, E. Cadot, Journal of Cluster Science, 2017, 1-14
Synthesis, biological evaluation and molecular modeling studies on novel quinonoid inhibitors of CDC25 phosphatases. E. Evain-Bana, L. Schiavo, C. Bour, D. A. Lanfranchi, S. Berardozzi, F. Ghirga, D. Bagrel, B. Botta, G. Hanquet, M. Mori, Journal of Enzyme Inhibition and Medicinal Chemistry, 2017, 32, 113
Acid-catalysed intramolecular addition of [small beta]-ketoesters to 1,3-dienes. M. Vayer, W. Fang, R. Guillot, S. Bezzenine-Lafollee, C. Bour, V. Gandon, Org. Biomol. Chem., 2017, 15, 584-588
Calcium‐Catalyzed Synthesis of Polysubstituted 2‐Alkenylfurans from β‐Keto Esters Tethered to Propargyl Alcohols. S. P. Morcillo, D. Lebœuf, C. Bour, V. Gandon, Chemistry – A European Journal, 2016, 22, 16974-16978
Stapled helical o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity. S. P. Morcillo, D. Miguel, L. Alvarez De Cienfuegos, J. Justicia, S. Abbate, E. Castiglioni, C. Bour, M. Ribagorda, D. J. Cardenas, J. M. Paredes, L. Crovetto, D. Choquesillo-Lazarte, A. J. Mota, M. C. Carreno, G. Longhi, J. M. Cuerva, Chem. Sci., 2016, 7, 5663-5670
Catalytic applications of [IPr[middle dot]GaX2][SbF6] and related species. B. Michelet, S. Tang, G. Thiery, J. Monot, H. Li, R. Guillot, C. Bour, V. Gandon, Org. Chem. Front., 2016, 3, 1603-1613
Site-Selective Calcium-Catalyzed/Organocatalyzed Condensation of Propargyl Alcohols Tethered to β-Keto Esters. S. P. Morcillo, M. Presset, S. Floquet, V. Coeffard, C. Greck, C. Bour, V. Gandon, European Journal of Organic Chemistry, 2016, 2016, 2688-2694
Copper (II) triflate as additive in low loading Au(I)-catalyzed hydroalkylation of unactivated alkenes. W. Fang, M. Presset, A. Guérinot, C. Bour, S. Bezzenine-Lafollée, V. Gandon, Organic Syntheses, 2015, 92, 117-130
CaII-Catalyzed Alkenylation of Alcohols with Vinylboronic Acids. D. Lebœuf, M. Presset, B. Michelet, C. Bour, S. Bezzenine-Lafollée, V. Gandon, Chemistry – A European Journal, 2015, 21, 11001-11005
Non-Innocent Behavior of Substrate Backbone Esters in Metal-Catalyzed Carbocyclizations and Friedel–Crafts Reactions of Enynes and Arenynes. B. Michelet, G. Thiery, C. Bour, V. Gandon, J. Org. Chem., 2015, 80, 10925-10938
New Procedures for Catalytic Carbophilic Activation by Gold and Gallium π-Acids. C. Bour, V. Gandon, Synlett, 2015, 26, 1427-1436
Gallium(III)- and calcium(II)-catalyzed Meyer-Schuster rearrangements followed by intramolecular aldol condensation or endo-Michael addition. M. Presset, B. Michelet, R. Guillot, C. Bour, S. Bezzenine-Lafollee, V. Gandon, Chem. Commun., 2015, 51, 5318-5321
First Evidence for the Existence of Hexafluoroantimonic(V) Acid. C. Bour, R. Guillot, V. Gandon, CHEMISTRY-A EUROPEAN JOURNAL, 2015, Volume: 21 Issue: 16, 6066-6069
Dibromoindium(III) cations as a pi-Lewis acid: characterization of [IPr center dot InBr2][SbF6] and its catalytic activity towards alkynes and alkenes. B. Michelet, J.-R. Colard-Itte, G. Thiery, R. Guillot, C. Bour, V. Gandon, CHEMICAL COMMUNICATIONS, 2015, Volume: 51 Issue: 34, 7401-7404
Silver-Free Two-Component Approach in Gold Catalysis: Activation of [LAuCl] Complexes with Derivatives of Copper, Zinc, Indium, Bismuth, and other Lewis Acids. W. Fang, M. Presset, A. Guerinot, C. Bour, S. Bezzenine-Lafollee, V. Gandon, Chemistry - A European Journal, 2014, 20, 5439-5446
Well-defined organo-gallium complexes as Lewis acids for molecular catalysis: Structure–stability–activity relationships. C. Bour, V. Gandon, Coordination Chemistry Reviews, 2014, 279, 43-57
Gallium-Assisted Transfer Hydrogenation of Alkenes. B. Michelet, C. Bour, V. Gandon, Chemistry – A European Journal, 2014, 20, 14488-14492
Cationic gold(i)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity. W. Fang, M. Presset, A. Guerinot, C. Bour, S. Bezzenine-Lafollee, V. Gandon, Org. Chem. Front., 2014, 1, 608-613
Structure, Stability, and Catalytic Activity of Fluorine-Bridged Complexes IPr·GaCl2(μ-F)EFn–1 (EFn– = SbF6–, PF6–, or BF4–). C. Bour, J. Monot, S. Tang, R. Guillot, J. Farjon, V. Gandon, Organometallics, 2014, 33, 594-599