Katell Senechal-David
Significant effect of 2nd sphere interactions on the reductive activation of O2 by non-heme iron(II) complexes. Application to the electroassisted oxidation of thioanisole. A. L. Robinson, E. Bannermann, R. Guillot, C. Herrero, K. Sénéchal-David, E. Rivière, F. Banse, J.-N. Rebilly, European Journal of Inorganic Chemistry, 2024, n/a, e202300694
Catalytic oxidation properties of an acid-resistant cross-bridged cyclen Fe(ii) complex. Influence of the rigid donor backbone and protonation on the reactivity. J.-N. Rebilly, C. Herrero, K. Sénéchal-David, R. Guillot, F. Banse, Dalton Trans., 2023, 52, 9017-9025
Second-sphere effects on H2O2 activation by non-heme FeII complexes: role of a phenol group in the [H2O2]-dependent accumulation of FeIVO vs. FeIIIOOH. J.-N. Rebilly, C. Herrero, K. Sénéchal-David, R. Guillot, T. Inceoglu, H. Maisonneuve, F. Banse, Chem. Sci., 2021, 12, 15691-15699
FeIII and FeII Phosphasalen Complexes: Synthesis, Characterization, and Catalytic Application for 2-Naphtol Oxidative Coupling. E. Oheix, C. Herrero, J. Moutet, J.-N. Rebilly, M. Cordier, R. Guillot, S. Bourcier, F. Banse, K. Sénéchal-David, A. Auffrant, Chemistry – A European Journal, 2020, 26, 13634-13643
Hydroxylation of Aromatics by H2O2 Catalyzed by Mononuclear Non-heme Iron Complexes: Role of Triazole Hemilability in Substrate-Induced Bifurcation of the H2O2 Activation Mechanism. J.-N. Rebilly, W. Zhang, C. Herrero, H. Dridi, K. Sénéchal-David, R. Guillot, F. Banse, Chemistry – A European Journal, 2020, 26, 659-668
Base-controlled mechanistic divergence between iron(iv)-oxo and iron(iii)-hydroperoxo in the H2O2 activation by a nonheme iron(ii) complex. A. Bohn, C. Chinaux-Chaix, K. Cheaib, R. Guillot, C. Herrero, K. Sénéchal-David, J.-N. Rebilly, F. Banse, Dalton Trans., 2019, 48, 17045-17051
Non-heme FeII diastereomeric complexes bearing a hexadentate ligand : unexpected consequences on the spin state and oxidation catalytic properties. K. Sénéchal-David, C. Buron, N. Ségaud, J.-N. Rebilly, A. Dos Santos, J. Farjon, R. Guillot, C. Herrero, T. Inceoglu, F. Banse, Chem. Eur. J., 2019, 25, 12405 – 12411
Selective Formation of an FeIVO or an FeIIIOOH Intermediate From Iron(II) and H2O2 : Controlled Heterolytic versus Homolytic Oxygen-Oxygen Bond Cleavage by the Second Coordination Sphere. K. Cheaib, M. Q. E. Mubarak, K. Sénéchal-David, C. Herrero, R. Guillot, M. Clémancey, J.-M. Latour, S. D. Visser, J.-P. Mahy, F. Banse, F. Avenier, Angew. Chem. Int. Ed., 2019, 58, 854-858
Synthesis and characterization of FeII complexes with a BPMEN type ligand bearing π-accepting nitro groups. A. Bohn, K. Sénéchal-David, J. Vanoutryve, R. Guillot, E. Rivière, F. Banse, European Journal of Inorganic Chemistry, 2017, 3057-3063
Mimicking the Regulation Step of Fe-Monooxygenases: Allosteric Modulation of FeIV-Oxo Formation by Guest Binding in a Dinuclear ZnII–FeII Calix[6]arene-Based Funnel Complex. N. Ségaud, C. De thomasson, C. Daverat, K. Sénéchal-David, A. Dos Santos, V. Steinmetz, P. Maître, J.-N. Rebilly, F. Banse, O. Reinaud, Chemistry – A European Journal, 2017, 23, 2894-2906
Self-assembled monolayer formation of a (N5)Fe(ii) complex on gold electrodes: electrochemical properties and coordination chemistry on a surface. C. Buron, S. Groni, N. Segaud, S. Mazerat, D. Dragoe, C. Fave, K. Senechal-David, B. Schollhorn, F. Banse, Dalton Trans., 2016, 45, 19053-19061
An Artificial Enzyme Made by Covalent Grafting of an FeII Complex into β-Lactoglobulin: Molecular Chemistry, Oxidation Catalysis, and Reaction-Intermediate Monitoring in a Protein. C. Buron, K. Sénéchal-David, R. Ricoux, J.-P. Le Caër, V. Guérineau, P. Méjanelle, R. Guillot, C. Herrero, J.-P. Mahy, F. Banse, Chem. Eur. J., 2015, 21, 12188-12193
Successive light-induced two electron transfers in a Ru-Fe supramolecular assembly: from Ru-Fe(ii)-OH2 to Ru-Fe(iv)-oxo. C. Herrero, A. Quaranta, M. Sircoglou, K. Senechal-David, A. Baron, I. M. Marin, C. Buron, J.-P. Baltaze, W. Leibl, A. Aukauloo, F. Banse, Chem. Sci., 2015, 6, 2323-2327
Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers. N. Segaud, E. Anxolabehere-Mallart, K. Senechal-David, L. Acosta-Rueda, M. Robert, F. Banse, Chem. Sci., 2015, 6, 639-647