Journal articles

2026

Ashutosh Vishwakarma, Sami Essid, Sarah Bouery, Régis Guillot, Bernard Boitrel, et al.. Directional Second Sphere Effect on CO₂ Activation and Reduction by Iron Porphyrin in Aprotic and Protic Media. Angewandte Chemie International Edition, In press, ⟨10.1002/anie.1490828⟩. ⟨hal-05706659⟩

Victor Crespin, Abir Jertila, Eric Daiann Sosa Carrizo, Elsa van Elslande, Tanguy Saget, et al.. Stereoselective β‐C‐aryl Glycosylation Through Ni‐Catalyzed Reductive Cross‐Coupling. ChemistryEurope, 2026, 4 (3), pp.e202500477. ⟨10.1002/ceur.202500477⟩. ⟨hal-05740111⟩

Louis Le Moigne, Marie Sircoglou, Quentin Bonnin, Marie‐josé Penouilh, Joan Vignolle, et al.. Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions. Angewandte Chemie International Edition, In press, ⟨10.1002/anie.4183926⟩. ⟨hal-05740055⟩

2025

Erwan Brunard, Vincent Boquet, Théo Bissonnier, Tanguy Saget, Eric Daiann Sosa Carrizo, et al.. Catalyst-Controlled Strategies to Override the BDE-Driven Selectivity of Benzylic C(sp 3 )-H Insertions. SYNLETT, 2025, ⟨10.1055/s-0043-1775407⟩. ⟨hal-05340513⟩

Adrien Smith, Philipp Gotico, Régis Guillot,, Stéphane Le Gac, Winfried Leibl, et al.. Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential. Advanced Science, 2025, pp.2500482. ⟨10.1002/advs.202500482⟩. ⟨hal-04919704⟩

2024

Erwan Brunard, Vincent Boquet, Tanguy Saget, E. Daiann Sosa Carrizo, Marie Sircoglou, et al.. Catalyst-Controlled Intermolecular Homobenzylic C(sp 3 )–H Amination for the Synthesis of β-Arylethylamines. Journal of the American Chemical Society, 2024, 146 (9), pp.5843-5854. ⟨10.1021/jacs.3c10964⟩. ⟨hal-04688858⟩

Sk Amanullah, Philipp Gotico, Marie Sircoglou, Winfried Leibl, Manuel Llansola-Portoles, et al.. Second Coordination Sphere Effect Shifts CO 2 to CO Reduction by Iron Porphyrin from Fe 0 to Fe I. Angewandte Chemie International Edition, 2024, 63 (4), pp.e202314439. ⟨10.1002/anie.202314439⟩. ⟨hal-04441669⟩

Daniel H Cruz Neto, Philipp Gotico, Thu-Trang Tran, Caroline Szantai, Zakaria Halime, et al.. Tracking photoinduced charge separation in a perfluorinated Zn-tetraphenylporphyrin sensitizer. New Journal of Chemistry, 2024, 48 (34), pp.14896-14903. ⟨10.1039/d4nj02484b⟩. ⟨hal-04735554⟩

2023

Vincent Boquet, Junio A Guimaraes Naves, Erwan A Brunard, Ali Nasrallah, Mylène Joigneaux, et al.. Rhodium(II)‐Catalyzed Selective C(sp 3 )−H Amination of Alkanes. European Journal of Organic Chemistry, 2023, 26 (32), ⟨10.1002/ejoc.202300352⟩. ⟨hal-04209991⟩

2022

Eva Pugliese, Nhat Tam Vo, Alain Boussac, Frédéric Banse, Yasmina Mekmouche, et al.. Photocatalytic generation of a non-heme Fe(III)-hydroperoxo species with O_2 in water for oxygen atom transfer reaction. Chemical Science, 2022, 2012, ⟨10.1039/D2SC03129A⟩. ⟨hal-03795563⟩

Vincent Boquet, Ali Nasrallah, Alejandro Dana, Erwan Brunard, Pablo Di Chenna, et al.. Rhodium(II)-Catalyzed Enantioselective Intermolecular Aziridination of Alkenes. Journal of the American Chemical Society, 2022, 144 (37), pp.17156-17164. ⟨10.1021/jacs.2c07337⟩. ⟨hal-03820483⟩

Eva Pugliese, Philipp Gotico, Iris Wehrung, Bernard Boitrel, Annamaria Quaranta, et al.. Dissection of light-induced charge accumulation at a highly active iron porphyrin: insights in the photocatalytic CO$_2$ reduction. Angewandte Chemie International Edition, 2022, 61 (14), pp.e202117530. ⟨10.1002/anie.202117530⟩. ⟨hal-03594100⟩

Philipp Gotico, Christian Herrero, Stefano Protti, Annamaria Quaranta, Sujitraj Sheth, et al.. Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad. Photochemical & Photobiological Sciences , 2022, 21 (2), pp.247-259. ⟨10.1007/s43630-021-00163-2⟩. ⟨hal-03865137⟩

2021

Nhat Tam Vo, Christian Herrero, Régis Guillot, Tanya Inceoglu, Winfried Leibl, et al.. Intercepting a Transient Pyridine N-Oxide Fe(III) Species in Catalytic Oxygen Atom Transfer Reaction. Chemical Communications, 2021, 57 (95), pp.12836-12839. ⟨10.1039/D1CC04521K⟩. ⟨hal-03678000⟩

Rajaa Farran, Yasmina Mekmouche, Nhat Tam Vo, Christian Herrero, Annamaria Quaranta, et al.. Tracking Light-Induced Electron Transfer towards O2 in a Hybrid Photoredox-Laccase System. iScience, 2021, pp.102378. ⟨10.1016/j.isci.2021.102378⟩. ⟨hal-03190584⟩

2020

Philipp Gotico, Loïc Roupnel, Regis Guillot, Marie Sircoglou, Winfried Leibl, et al.. Atropisomeric Hydrogen Bonding Control for CO 2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins. Angewandte Chemie International Edition, 2020, ⟨10.1002/anie.202010859⟩. ⟨hal-03016806⟩

2019

Nhat Tam Vo, Yasmina Mekmouche, Thierry Tron, Régis Guillot, Frédéric Banse, et al.. A Reversible Electron Relay to Exclude Sacrificial Electron Donors in the Photocatalytic Oxygen Atom Transfer Reaction with O 2 in Water. Angewandte Chemie, 2019, 131 (45), pp.16169-16173. ⟨10.1002/ange.201907337⟩. ⟨hal-05771143⟩

Philipp Gotico, Bernard Boitrel, Régis Guillot, Marie Sircoglou, Annamaria Quaranta, et al.. Frontispiz: Second‐Sphere Biomimetic Multipoint Hydrogen‐Bonding Patterns to Boost CO 2 Reduction of Iron Porphyrins. Angewandte Chemie, 2019, 131 (14), ⟨10.1002/ange.201981461⟩. ⟨hal-05771102⟩

Philipp Gotico, Bernard Boitrel, Régis Guillot, Marie Sircoglou, Annamaria Quaranta, et al.. Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins. Angewandte Chemie International Edition, 2019, 58 (14), pp.4504-4509. ⟨10.1002/anie.201814339⟩. ⟨hal-02050269⟩

Philipp Gotico, Bernard Boitrel, Régis Guillot, Marie Sircoglou, Annamaria Quaranta, et al.. Second‐Sphere Biomimetic Multipoint Hydrogen‐Bonding Patterns to Boost CO 2 Reduction of Iron Porphyrins. Angewandte Chemie, 2019, 131 (14), pp.4552-4557. ⟨10.1002/ange.201814339⟩. ⟨hal-05771095⟩

Nhat Tam Vo, Yasmina Mekmouche, Thierry Tron, Régis Guillot, Frédéric Banse, et al.. A Reversible Electron Relay to Exclude Sacrificial Electron Donors in the Photocatalytic Oxygen Atom Transfer Reaction with O2 in Water. Angewandte Chemie International Edition, 2019, ⟨10.1002/anie.201907337⟩. ⟨hal-02301619⟩

2018

Georgios Chararalambidis, Shyamal Das, Adelais Trapali, Annamaria Quaranta, Maylis Orio, et al.. Water Molecules Gating a Photoinduced One‐Electron Two‐Protons Transfer in a Tyrosine/Histidine (Tyr/His) Model of Photosystem II. Angewandte Chemie, 2018, 130 (29), pp.9151-9155. ⟨10.1002/ange.201804498⟩. ⟨hal-05771039⟩

Georgios Chararalambidis, Syamal Das, Adelais Trapali, Annamaria Quaranta, Maylis Orio, et al.. Water Molecules Gating a Photoinduced One Electron Two Protons Transfer in a Tyr/His model of Photosystem II. Angewandte Chemie International Edition, 2018, ⟨10.1002/anie.201804498⟩. ⟨hal-02176998⟩

2017

Rajaa Farran, Clémence Ducloiset, Julien Buendia, Nhat Tam Vo, Régis Guillot, et al.. Light-Induced Activation of the Du Bois [Rh ^\textrmII _\textrm2 (Esp) _\textrm2 ] Catalyst for Nitrogen Atom Transfer Reactions. ChemPhotoChem, 2017, 1 (12), pp.562–567. ⟨10.1002/cptc.201700138⟩. ⟨hal-02281873⟩

2015

Christian Herrero, Annamaria Quaranta, Marie Sircoglou, Katell Sénéchal-David, Aurélie Baron, et al.. Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(II)–OH2 to Ru–Fe(IV)–oxo. Chemical Science, 2015, ⟨10.1039/C5SC00024F⟩. ⟨hal-01450312⟩

C. Ducloiset, P. Jouin, E. Paredes, R. Guillot, M. Sircoglou, et al.. Monoanionic dipyrrin-pyridine ligands: Synthesis, structure and photophysical properties. European Journal of Inorganic Chemistry, 2015, 2015, pp.5405 – 5410. ⟨10.1002/ejic.201500783⟩. ⟨hal-01261536⟩

2013

Amandine Guérinot, Weizhen Fang, Marie Sircoglou, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Copper Salts as Additives in Gold(I)‐Catalyzed Reactions. Angewandte Chemie International Edition, 2013, 52 (22), pp.5848-5852. ⟨10.1002/anie.201300600⟩. ⟨hal-05415377⟩

Marie Sircoglou, Jing Yang, Régis Guillot, Sophie Bezzenine-Lafollée, Vincent Gandon. Heterobimetallic Rare Earth–Lithium Complexes with Fewer Than Three Binaphtholates. European Journal of Inorganic Chemistry, 2013, 2013 (15), pp.2807-2811. ⟨10.1002/ejic.201300201⟩. ⟨hal-05415376⟩

M. Sircoglou, N. Saffon, Karinne Miqueu, G. Bouhadir, D. Bourissou. Activation of M-Cl bonds with phosphine-alanes: Preparation and characterization of zwitterionic gold and copper complexes. Organometallics, 2013, 32 (22), pp.6780-6784. ⟨10.1021/om4005884⟩. ⟨hal-01613228⟩

C. Herrero, L. Batchelor, A. Baron, Sanae El Ghachtouli, S. Sheth, et al.. Click chemistry as a convenient tool for the incorporation of a ruthenium chromophore and a nickel-salen monomer into a visible-light-active assembly. European Journal of Inorganic Chemistry, 2013, 2013 (4), pp.494-499. ⟨10.1002/ejic.201201161⟩. ⟨hal-00783664⟩

2011

E.J. Derrah, M. Sircoglou, Maxime Mercy, S. Ladeira, G. Bouhadir, et al.. Original transition metal→indium interactions upon coordination of a triphosphine-indane. Organometallics, 2011, 30 (4), pp.657-660. ⟨10.1021/om1011769⟩. ⟨hal-01613240⟩

2010

M. Sircoglou, Sébastien Bontemps, Maxime Mercy, Karinne Miqueu, S. Ladeira, et al.. Copper(I) complexes derived from mono- and diphosphino-boranes: Cu→b interactions supported by arene coordination. Inorganic Chemistry, 2010, 49 (9), pp.3983-3990. ⟨10.1021/ic901896z⟩. ⟨hal-01613247⟩

2009

G. Bouhadir, Laurent Maron, Maxime Mercy, Nathalie Saffon, Marie Sircoglou, et al.. Gold(I) complexes of phosphanyl-gallanes: from interconverting to separable coordination isomers. Angewandte Chemie International Edition, 2009, 48, pp.3454-3457. ⟨hal-00443926⟩

Pauline Gualco, T.P Lin, Maxime Mercy, Marie Sircoglou, Sonia Ladeira, et al.. Gold→Silane and Gold→Stannane Complexes: Coordination of Saturated Molecules as Acceptor Ligands. Angewandte Chemie International Edition, 2009, 48, pp.9892-9895. ⟨hal-00458851⟩

2008

M. Sircoglou, Sébastien Bontemps, G. Bouhadir, N. Saffon, Karinne Miqueu, et al.. Group 10 and 11 metal boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au +) derived from a triphosphine-borane. Journal of the American Chemical Society, 2008, 130 (49), pp.16729-16738. ⟨10.1021/ja8070072⟩. ⟨hal-01613260⟩

G. Bouhadir, D. Bourissou, Karinne Miqueu, Nathalie Saffon, Marie Sircoglou. A Zwitterionic gold(I) complex from an ambiphilic diphosphino-alane ligand. Organometallics, 2008, 27, pp.1675-1678. ⟨hal-00345518⟩

Sylvain Bontemps, Marie Sircoglou, G. Bouhadir, Horst Puschmann, Judith A.K. Howard, et al.. Ambiphilic diphosphine-borane ligands : metal borane interactions with in isoelectronic complexes of rhodium, platinum and palladium. Chemistry – A European Journal, 2008, 14 (2), pp.731-740. ⟨10.1002/chem.200701027⟩. ⟨hal-00266194⟩

2007

Nathalie Saffon, Marie Sircoglou, Sébastien Bontemps, G. Bouhadir, Laurent Maron, et al.. Transition-metal complexes featuring Z-type ligands : agreement or discrepancy between geometry and dn configuration ?. Angewandte Chemie, 2007, 46, pp.8583-8586. ⟨hal-00266276⟩

Conference papers

2025

M. Sircoglou. Selective nitrene transfer controlled by Rh2 catalyst : what computational investigations can teach us?. GECO, Aug 2025, Evian-les-bains, France. ⟨hal-05685287⟩

2024

M. Sircoglou. Metal-ligand cooperativity and Second-sphere effects in Catalysis. Gecom-Concoord, May 2024, Ax-Les-Thermes, France. ⟨hal-05752270⟩

2023

Philippe Dauban, Vincent Boquet, Erwan Brunard, Ali Nasrallah, Tanguy Saget, et al.. C4-Symmetrical Rhodium(II) complexes and sulfamates for catalytic selective C-N bond forming reactions. Congrès SCF 2023, Société Chimique de France, Jun 2023, Nantes, France. ⟨hal-04434767⟩

2008

Magnus Bebbington, Sylvain Bontemps, G. Bouhadir, D. Bourissou, Sylvie Moebs-Sanchez, et al.. Ambiphilic phosphine-boranes : from the bridging coordination of metal fragments to the stabilisation of reactive intermediates. Ambiphilic phosphine-boranes : from the bridging coordination of metal fragments to the stabilisation of reactive intermediates, Nov 2008, CORCELLES-LES-MONTS, France. ⟨hal-00380249⟩

Sylvain Bontemps, G. Bouhadir, D. Bourissou, Laurent Maron, Karinne Miqueu, et al.. Metal boron interactions from ambiphilic phosphine-borane ligands. Metal boron interactions from ambiphilic phosphine-borane ligands, Sep 2008, Spain. ⟨hal-00378985⟩

Magnus Bebbington, Sylvain Bontemps, G. Bouhadir, D. Bourissou, Sylvie Moebs-Sanchez, et al.. Ambiphilic phosphine-boranes : from the bridging coordination of metal fragments to the stabilisation of reactive intermediates. Ambiphilic phosphine-boranes : from the bridging coordination of metal fragments to the stabilisation of reactive intermediates, Sep 2008, bordeaux, France. ⟨hal-00380237⟩

Sylvain Bontemps, G. Bouhadir, D. Bourissou, Laurent Maron, Karinne Miqueu, et al.. Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation. Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation, Aug 2008, Rennes, France. ⟨hal-00399259⟩

G. Bouhadir, D. Bourissou, Marie Sircoglou. Ambiphilic ligands : tuneable coordination modes. Ambiphilic ligands : tuneable coordination modes, Mar 2008, Germany. ⟨hal-00346438⟩

Poster communications

2023

M. Sircoglou, E. Daiann Sosa Carrizo. Effect of axial solvent coordination to Rh2-nitrene species relevant to catalytic C-H amination. ESOR, Sep 2023, Amsterdam (NETHERLANDS), France. ⟨hal-05752279⟩

Pre-publications

2025

Victor Crespin, Abir Jertila, Eric Daiann Sosa Carrizo, Elsa van Elslande, Tanguy Saget, et al.. Stereoselective β-C-aryl glycosylation through Ni-catalysed reductive cross-coupling. 2025. ⟨hal-05368345⟩

Theses

2009

Marie Sircoglou. Etude des modes de coordination des ligands ambiphiles PE (E = B, Al, Ga). Autre. Université Paul Sabatier – Toulouse III, 2009. Français. ⟨NNT : ⟩. ⟨tel-00450170⟩

Habilitation à diriger des recherches

2023

Marie Sircoglou. Coopérativité métal-ligand en catalyse : Quelques clés de compréhension. Chimie. Université Paris Saclay, 2023. ⟨tel-05499235⟩