Martial Toffano

Journal articles

2026

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Sihem Hessainia, Houda Bouraoui, Samia Guezane Lakoud, Fares Hamoud, Amel Sedik, et al.. Tailored diastereomeric ibuprofen acetoxyphosphonates: Design, synthesis, anti-inflammatory and antimicrobial activities, SAR, DFT, and molecular docking studies. Journal of Molecular Structure, 2026, 1365, pp.145984. ⟨10.1016/j.molstruc.2026.145984⟩. ⟨hal-05566040⟩

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Zhiwei Jiang, Martial Toffano, Régis Guillot, Chloée Bournaud, Giang Vo-Thanh. N-Heterocyclic Carbene-Catalyzed Generation of Homoenolates: Efficient Asymmetric Synthesis of Dispirocyclopentanones by Direct Annulation of Enals and Isoindigos. Catalysts, 2026, 16 (2), pp.138. ⟨10.3390/catal16020138⟩. ⟨hal-05523376⟩

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2025

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Nabila Braia, Samia Guezane Lakoud, Fares Hamoud, Houda Bouraoui, Abdelaziz Ladjimi, et al.. Design, X-ray crystal structure, Hirshfeld surface analysis, in vitro biological evaluation, DFT and molecular docking studies of 3,4,5-trimethoxyphenyl α-acetoxymethyl phosphonates. Journal of Molecular Structure, 2025, 1347, pp.143304. ⟨10.1016/j.molstruc.2025.143304⟩. ⟨hal-05363608⟩

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Samia Guezane Lakoud, Nourhane Touil, Houda Bouraoui, Fares Hamoud, Hizia Harem, et al.. Furan α-acetoxy methylphosphonates: Design and synthesis, in vitro antibacterial and antifungal activities, DFT, topology exploration (ELF, LOL, RDG) and molecular docking. Journal of Molecular Structure, 2025, 1327, pp.141216. ⟨10.1016/j.molstruc.2024.141216⟩. ⟨hal-05363543⟩

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2024

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Chloée Bournaud, Martial Toffano, Giang Vo-Thanh. Organocatalyse énantiosélective par des catalyseurs bifonctionnels : concept et développements. L’Actualité Chimique, 2024, 497, pp.20-23. ⟨hal-04761002⟩

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Samia Guezane-Lakoud, Meriem Ferrah, Mounia Merabet-Khelassi, Nourhane Touil, Martial Toffano, et al.. 2-Hydroxymethyl-18-crown-6 as an efficient organocatalyst for α – aminophosphonates synthesized under eco-friendly conditions, DFT, molecular docking and ADME/T studies. Journal of Biomolecular Structure and Dynamics, 2024, 42 (7), pp.3332-3348. ⟨10.1080/07391102.2023.2213336⟩. ⟨hal-04236980⟩

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Fatma Zohra Smaine, Mounia Merabet-Khelassi, Saoussen Zeror, Emilie Kolodziej, Martial Toffano, et al.. Fatty and aromatic acids as acyl donors in enzymatic kinetic resolution of phenylethanol and 1-phenylpropan-2-ol. Chemical Monthly = Monatshefte für Chemie, 2024, 155 (1), pp.105-113. ⟨10.1007/s00706-023-03147-3⟩. ⟨hal-04760950⟩

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Stéphane Wittmann, Elodie Deschamps, Chloée Bournaud, Regis Guillot, Jean-François Brière, et al.. Auto tandem triple cascade organocatalysis: Access to bis-lactone and butenolide derivatives. Chemical Communications, 2024, 60, pp.9278-9281. ⟨10.1039/D4CC03029J⟩. ⟨hal-04700648⟩

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2023

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Meriem Farreh, Samia Guezane-Lakoud, Hacene Bendjeffal, Rym Aissa, Mounia Merabet-Khelassi, et al.. Full factorial optimization of α-aminophosphonates synthesis using diphenylphosphinic acid as efficient Organocatalyst. Reaction kinetics, mechanisms and catalysis, 2023, 136 (1), pp.165-183. ⟨10.1007/s11144-022-02329-0⟩. ⟨hal-04237813⟩

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2022

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Rim Aissa, Samia Guezane-Lakoud, Lynda Gali, Martial Toffano, Anna Ignaczak, et al.. New promising generation of phosphates α-aminophosphonates : Design, synthesis, in-vitro biological evaluation and computational study. Journal of Molecular Structure, 2022, 1247, pp.131336. ⟨10.1016/j.molstruc.2021.131336⟩. ⟨hal-03815145⟩

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Nabila Braia, Mounia Merabet-Khelassi, Martial Toffano, Régis Guillot, Louisa Aribi-Zouioueche. Access to valuable building blocks by regio-and enantioselective ring-opening of itaconic anhydride using lipase catalysis.. Organic & Biomolecular Chemistry, 2022, ⟨10.1039/D2OB00047D⟩. ⟨hal-03603787⟩

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Nabila Braïa, Mounia Merabet-Khelassi, Martial Toffano, Louisa Aribi-Zouioueche. Practical access to (S)- heterocyclic aromatic acetates via CAL-B /Na 2 CO 3 -deacylation and Mitsunobu reaction protocol. Biocatalysis and Biotransformation, 2022, pp.1-9. ⟨10.1080/10242422.2022.2030726⟩. ⟨hal-03578388⟩

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2021

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Rim Aissa, Samia Guezane-Lakoud, Martial Toffano, Lynda Gali, Louisa Aribi-Zouioueche. Fiaud’s Acid, a novel organocatalyst for diastereoselective bis α-aminophosphonates synthesis with in-vitro biological evaluation of antifungal, antioxidant and enzymes inhibition potential. Bioorganic and Medicinal Chemistry Letters, 2021, 41, pp.128000. ⟨10.1016/j.bmcl.2021.128000⟩. ⟨hal-03304159⟩

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Louis Chassillan, Yasuhiro Yamashita, Woo-Jin Yoo, Martial Toffano, Régis Guillot, et al.. Enantioselective hydrophosphonylation of N -Boc imines using chiral guanidine–thiourea catalysts. Organic & Biomolecular Chemistry, 2021, 19 (48), pp.10560-10564. ⟨10.1039/D1OB01953H⟩. ⟨hal-03815260⟩

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Zhiwei Jiang, Martial Toffano, Giang Vo‐thanh, Chloée Bournaud. Bifunctional N‐Heterocylic Carbene‐Catalyzed Highly Enantioselective Trans‐Cyclopentannulation of Enals and Enones via Homoenolate. ChemCatChem, 2021, 13 (2), pp.712-717. ⟨10.1002/cctc.202001513⟩. ⟨hal-03303929⟩

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Samra Razi, Saoussen Zeror, Mounia Merabet-Khelassi, Emilie Kolodziej, Martial Toffano, et al.. Two Approaches for CAL-B-Catalyzed Enantioselective Deacylation of a Set of α-Phenyl Ethyl Esters: Organic Solvent with Sodium Carbonate and Micro-aqueous Medium. Catalysis Letters, In press, ⟨10.1007/s10562-020-03525-0⟩. ⟨hal-03304163⟩

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Martial Toffano, Régis Guillot, Chloee Bournaud, Jean-François Brière, Giang Vo-Thanh. Auto Tandem Catalysis: Asymmetric Vinylogous Cycloaddition / Kinetic Resolution Sequence for the Enantioselective Synthesis of Spiro‐Dihydropyranone from Benzylidene Meldrum’s Acid. Advanced Synthesis and Catalysis, 2021, 363, pp.4452-4458. ⟨10.1002/adsc.202100559⟩. ⟨hal-03304167⟩

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Stéphane Wittmann, Thomas Martzel, Cong Thanh Pham Truong, Martial Toffano, Sylvain Oudeyer, et al.. Alkylidene Meldrum’s Acids as Platforms for the Vinylogous Synthesis of Dihydropyranones. Angewandte Chemie International Edition, 2021, 60, pp.11110-11114. ⟨10.1002/anie.202014489⟩. ⟨hal-03200519⟩

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2020

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Samia Guezane Lakoud, Rim Aissa, Regis Guillot, Martial Toffano, L. Aribi‐zouioueche. Novel One-Pot Access to Diastereoisomeric Tertiary Phospholanes Oxides by Using Enantiomerically Pure Phospholane Oxides Under Catalyst-Free Conditions. ChemistrySelect, 2020, 5 (1), pp.379-383. ⟨10.1002/slct.201903760⟩. ⟨hal-03019308⟩

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2019

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Rim Aissa, Samia Guezane-Lakoud, Emilie Kolodziej, Martial Toffano, Louisa Aribi-Zouioueche. Diastereoselective synthesis of bis(α-aminophosphonates) by lipase catalytic promiscuity. New Journal of Chemistry, 2019, 43 (21), pp.8153-8159. ⟨10.1039/c8nj06235h⟩. ⟨hal-02359964⟩

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Rim Aissa, Samia Guezane-Lakoud, Emilie Kolodziej, Martial Toffano, Louisa Aribi-Zouioueche. Diastereoselective synthesis of bis(α-aminophosphonates) by lipase catalytic promiscuity. New Journal of Chemistry, 2019, 43 (21), pp.8153-8159. ⟨10.1039/C8NJ06235H⟩. ⟨hal-03303378⟩

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Thi Thuy Duong Ngo, Khanh Duy Huynh, Houssein Ibrahim, Thi Huong Nguyen, Chloée Bournaud, et al.. Chiral catalysts derived from biomass: design, synthesis and applications in asymmetric catalysis. Vietnam Journal of Chemistry, 2019, 57 (6), pp.670-680. ⟨10.1002/vjch.201900177⟩. ⟨hal-03019278⟩

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2018

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Anne-Laure Barthelemy, Alexis Prieto, Patrick Diter, Jérôme Hannedouche, Martial Toffano, et al.. Facile Preparation of Vinyl S -Trifluoromethyl N H Aryl Sulfoximines. European Journal of Organic Chemistry, 2018, 2018 (27-28), pp.3764-3770. ⟨10.1002/ejoc.201800324⟩. ⟨hal-02358294⟩

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Lucie Bouchardy, Violeta Rodriguez-Ruiz, Chloée Bournaud, François-Didier Boyer, Martial Toffano, et al.. Novel class of reversible chiral ionic liquids derived from natural amino acids: synthesis and characterization. ChemistrySelect, 2018, 3 (3), pp.958-962. ⟨10.1002/slct.201702708⟩. ⟨hal-01941218⟩

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Alexis Prieto, Patrick Diter, Martial Toffano, Jérôme Hannedouche, Emmanuel Magnier. Photoredox‐Initiated 1,2‐Difunctionalization of Alkenes with N ‐Chloro S ‐Fluoroalkyl Sulfoximines. Advanced Synthesis and Catalysis, 2018, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩. ⟨hal-02358288⟩

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2016

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Thanh-Nghi Le, Patrick Diter, Bruce Pégot, Chloée Bournaud, Martial Toffano, et al.. S -Trifluoromethyl Sulfoximine as a Directing Group in Ortho -Lithiation Reaction toward Structural Complexity. Organic Letters, 2016, 18 (19), pp.5102-5105. ⟨10.1021/acs.orglett.6b02548⟩. ⟨hal-05130984⟩

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2015

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Thanh-Nghi Le, Patrick Diter, Bruce Pégot, Chloée Bournaud, Martial Toffano, et al.. Functionalized S-perfluorinated sulfoximines: Preparation and evaluation in catalytic processes. Journal of Fluorine Chemistry, 2015, 179, pp.179-187. ⟨10.1016/j.jfluchem.2015.06.020⟩. ⟨hal-05131389⟩

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2014

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Thanh-Nghi Le, Emilie Kolodziej, Patrick Diter, Bruce Pégot, Chloée Bournaud, et al.. First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines. CHIMIA, 2014, 68 (6), pp.410. ⟨10.2533/chimia.2014.410⟩. ⟨hal-05121417⟩

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2013

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Yohan Macé, Céline Constant-Urban, Sébastien Bouvet, Bruce Pégot, Chloée Bournaud, et al.. A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines. Synthesis: Journal of Synthetic Organic Chemistry, 2013, 45 (11), pp.1505-1512. ⟨10.1055/s-0033-1338440⟩. ⟨hal-05131369⟩

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2011

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Yohan Macé, Bruce Pégot, Régis Guillot, Chloée Bournaud, Martial Toffano, et al.. Efficient copper-induced coupling between NH-fluoroalkylated sulfoximines and aryl iodides or bromides. Tetrahedron, 2011, 67 (39), pp.7575-7580. ⟨10.1016/j.tet.2011.07.060⟩. ⟨hal-05123370⟩

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2002

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F. Guillen, Michael Rivard, Martial Toffano, Jean-Yves Legros, Jean-Claude Daran, et al.. Synthesis and first applications of a new family of chiral monophosphine ligand: 2,5-diphenylphosphospholanes. Tetrahedron, 2002, 58 (29), pp.5895. ⟨10.1016/S0040-4020(02)00554-9⟩. ⟨hal-01146983⟩

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1997

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Jean-Yves Legros, Martial Toffano, Sally K. Drayton, Michael Rivard, Jean-Claude Fiaud. Kinetic Resolution of Secondary Alcohols Mediated by Rabbit Gastric Lipase. Tetrahedron Letters, 1997, 38 (11), pp.1915-1918. ⟨10.1016/S0040-4039(97)00242-6⟩. ⟨hal-04013327⟩

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