Christophe Bour

Journal articles

2025

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Xiangmeng Chen, Christophe Bour, Emilie Kolodziej, Regis Guillot, Nicolas George, et al.. Calcium(II)‐Catalyzed Synthesis of Sulfoximinocyclopentenones. Advanced Synthesis and Catalysis, 2025, 367 (2), pp.e202401085. ⟨10.1002/adsc.202401085⟩. ⟨hal-04833750⟩

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Arnaud Espied, Djamila Azrou, Régis Guillot, Aurélien Alix, Vincent Gandon, et al.. Lewis Acid‐Catalyzed Tandem Cyclizations of 1,2‐Diarylalkenols. Advanced Synthesis and Catalysis, 2025, 367 (17), ⟨10.1002/adsc.70065⟩. ⟨hal-05418657⟩

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2024

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Wenhua Lin, Aurélien Alix, Régis Guillot, Vincent Gandon, Christophe Bour. Aluminum-Catalyzed Intramolecular Vinylation of Arenes by Vinyl Cations. Organic Letters, 2024, 26 (15), pp.3267-3272. ⟨10.1021/acs.orglett.4c00889⟩. ⟨hal-04587150⟩

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2022

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Yan Chen, Vincent Gandon, Christophe Bour. Squaramide/Li + -Catalyzed Direct S N 1-Type Reaction of Vinyl Triflates with Difluoroenoxysilanes through Vinyl Cations. Organic Letters, 2022, 24 (38), pp.6978-6982. ⟨10.1021/acs.orglett.2c02793⟩. ⟨hal-04477720⟩

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Quentin Gaignard Gaillard, Xu Han, Aurélien Alix, Christophe Bour, Régis Guillot,, et al.. Atroposelective Synthesis of Tetrahydropyrrolo[3,2‐c]azepine Derivatives Through Gold(I)‐Catalyzed Hydroarylation. Advanced Synthesis and Catalysis, 2022, 364 (24), pp.4415-4420. ⟨10.1002/adsc.202200828⟩. ⟨hal-04265403⟩

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Jiaxin Tian, Marie Cordier, Christophe Bour, Audrey Auffrant, Vincent Gandon. A Cyclic Divalent N(I) Species Isoelectronic to Carbodiphosphoranes. Chemical Communications, 2022, 58 (38), pp.5741-5744. ⟨10.1039/D2CC01637K⟩. ⟨hal-03766696⟩

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Marie Vayer, Sophie Rodrigues, Solène Miaskiewicz, David Gatineau, Yves Gimbert, et al.. Potassium Carbonate to Unlock a GaCl 3 -Catalyzed C-H Propargylation of Arenes. ACS Catalysis, 2022, 12 (1), pp.305-315. ⟨10.1021/acscatal.1c03014⟩. ⟨hal-03722704⟩

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Shengwen Yang, Solène Miaskiewicz, Christophe Bour, Aurélien Alix, Vincent Gandon. Transition structures for the oxy–ene reaction. Chemical Communications, 2022, 58 (30), pp.4751-4754. ⟨10.1039/D2CC00687A⟩. ⟨hal-04477826⟩

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2021

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Shengdong Wang, Guillaume Force, Jean-François Carpentier, Yann Sarazin, Christophe Bour, et al.. Modular Synthesis of 9,10-Dihydroacridines through an ortho-C Alkenylation/Hydroarylation Sequence between Anilines and Aryl Alkynes in Hexafluoroisopropanol. Organic Letters, 2021, 23 (7), pp.2565-2570. ⟨10.1021/acs.orglett.1c00487⟩. ⟨hal-03245060⟩

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Shengwen Yang, Christophe Bour, David Lebœuf, Vincent Gandon. DFT Analysis into the Calcium(II)-Catalyzed Coupling of Alcohols With Vinylboronic acids: Cooperativity of Two Different Lewis Acids and Counterion Effects. Journal of Organic Chemistry, 2021, 86 (13), pp.9134-9144. ⟨10.1021/acs.joc.1c01263⟩. ⟨hal-03401941⟩

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Shengwen Yang, Aurélien Alix, Christophe Bour, Vincent Gandon. Alkynophilicity of Group 13 MX 3 Salts: A Theoretical Study. Inorganic Chemistry, 2021, 60 (8), pp.5507-5522. ⟨10.1021/acs.inorgchem.0c03302⟩. ⟨hal-04477926⟩

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2020

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Joanna Hammoud, Fatima Abou-Khalil, Thierry Roisnel, Vincent Dorcet, Christophe Bour, et al.. Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s. Dalton Transactions, 2020, 49 (37), pp.13017-13028. ⟨10.1039/d0dt02573a⟩. ⟨hal-02959795⟩

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Zhilong Li, Shengwen Yang, Guillaume Thiery, Vincent Gandon, Christophe Bour. On the Superior Activity of In(I) versus In(III) Cations Toward ortho-C- Alkylation of Anilines and Intramolecular Hydroamination of Alkenes. Journal of Organic Chemistry, 2020, 85 (20), pp.12947-12959. ⟨10.1021/acs.joc.0c01585⟩. ⟨hal-04477981⟩

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Zhilong Li, Vincent Gandon, Christophe Bour. Bimolecular vinylation of arenes by vinyl cations. Chemical Communications, 2020, 56 (48), pp.6507-6510. ⟨10.1039/D0CC02300K⟩. ⟨hal-02919135⟩

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Jiaxin Tian, Yan Chen, Marie Vayer, Alexandre Djurovic, Régis Guillot, et al.. Exploring the Limits of π‐Acid Catalysis Using Strongly Electrophilic Main Group Metal Complexes: The Case of Zinc and Aluminium. Chemistry – A European Journal, 2020, 26 (56), pp.12831-12838. ⟨10.1002/chem.202001376⟩. ⟨hal-03097839⟩

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Marie Vayer, Christophe Bour, Vincent Gandon. Exploring the Versatility of 7‐Alkynylcycloheptatriene Scaffolds Under π‐Acid Catalysis. European Journal of Organic Chemistry, 2020, 2020 (33), pp.5350-5357. ⟨10.1002/ejoc.202000623⟩. ⟨hal-04595699⟩

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Shengdong Wang, Régis Guillot, Jean-François Carpentier, Yann Sarazin, Christophe Bour, et al.. Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence. Angewandte Chemie International Edition, 2020, 59 (3), pp.1134-1138. ⟨10.1002/anie.201911761⟩. ⟨hal-02438534⟩

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Shengdong Wang, Guillaume Force, Régis Guillot, Jean-François Carpentier, Yann Sarazin, et al.. Lewis Acid/Hexafluoroisopropanol: A Promoter System for Selective ortho-C-Alkylation of Anilines with Deactivated Styrene Derivatives and Unactivated Alkenes. ACS Catalysis, 2020, 10 (18), pp.10794-10802. ⟨10.1021/acscatal.0c02959⟩. ⟨hal-02961178⟩

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Shengwen Yang, Christophe Bour, Vincent Gandon. Superelectrophilic Gallium(III) Homodimers in Gallium Chloride-Mediated Methylation of Benzene: A Theoretical Study. ACS Catalysis, 2020, 10 (5), pp.3027-3033. ⟨10.1021/acscatal.9b05509⟩. ⟨hal-02919128⟩

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2019

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Alexandre Djurovic, Marie Vayer, Zhilong Li, Régis Guillot, Jean-Pierre J.-P. Baltaze, et al.. Synthesis of Medium-Sized Carbocycles by Gallium-Catalyzed Tandem Carbonyl–Olefin Metathesis/Transfer Hydrogenation. Organic Letters, 2019, 21 (19), pp.8132-8137. ⟨10.1021/acs.orglett.9b03240⟩. ⟨hal-02331912⟩

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2018

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Ghanem Hamdoun, Ludmilla Guduff, Carine van Heijenoort, Christophe Bour, Vincent Gandon, et al.. Spatially encoded diffusion-ordered NMR spectroscopy of reaction mixtures in organic solvents. Analyst, 2018, 143 (14), pp.3458-3464. ⟨10.1039/C8AN00434J⟩. ⟨hal-02392883⟩

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Ghanem Hamdoun, Christophe Bour, Vincent Gandon, Jean-Nicolas Dumez. Empirical Estimation of the Molecular Weight of Gold Complexes in Solution by Pulsed-Field Gradient NMR. Organometallics, 2018, 37 (24), pp.4692-4698. ⟨10.1021/acs.organomet.8b00709⟩. ⟨hal-01999514⟩

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Manish Pareek, Christophe Bour, Vincent Gandon. Gallium-Catalyzed Scriabine Reaction. Organic Letters, 2018, 20 (21), pp.6957-6960. ⟨10.1021/acs.orglett.8b03104⟩. ⟨hal-01999490⟩

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Marie Vayer, Sara Morcillo, Jennifer Dupont, Vincent Gandon, Christophe Bour. Iron-Catalyzed Reductive Ethylation of Imines with Ethanol. Angewandte Chemie International Edition, 2018, 57 (12), pp.3228-3232. ⟨10.1002/anie.201800328⟩. ⟨hal-01999387⟩

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Marie Vayer, Régis Guillot, Christophe Bour, Vincent Gandon. Synthesis of 3-Substituted 3-Bromo-1-phenylallenes from Alkynylcycloheptatrienes. Journal of Organic Chemistry, 2018, 83 (18), pp.11309-11317. ⟨10.1021/acs.joc.8b01498⟩. ⟨hal-05415600⟩

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2017

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Mouhamad Awada, Sébastien Floquet, Jérôme Marrot, Mohamed Haouas, Sara Morcillo, et al.. Synthesis and Characterizations of Keplerate Nanocapsules Incorporating L- and D-Tartrate Ligands. Journal of Cluster Science, 2017, 28 (2), pp.799-812. ⟨10.1007/s10876-017-1171-7⟩. ⟨hal-05415400⟩

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E Evain-Bana, Lucie Schiavo, C Bour, Don Antoine Lanfranchi, S Berardozzi, et al.. Synthesis, biological evaluation and molecular modeling studies on novel quinonoid inhibitors of CDC25 phosphatases. Journal of Enzyme Inhibition and Medicinal Chemistry, 2017, 32, pp.113-118. ⟨10.1080/14756366.2016.1238364⟩. ⟨hal-02161666⟩

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Zhilong Li, Guillaume Thiery, Martin Lichtenthaler, Régis Guillot, Ingo Krossing, et al.. Catalytic Use of Low‐Valent Cationic Gallium(I) Complexes as π‐Acids. Advanced Synthesis and Catalysis, 2017, 360 (3), pp.544-549. ⟨10.1002/adsc.201701081⟩. ⟨hal-05415409⟩

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Bastien Michelet, David Lebœuf, Christophe Bour, Karel Škoch, Filip Horký, et al.. Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands. ChemPlusChem, 2017, 82 (3), pp.442-448. ⟨10.1002/cplu.201600562⟩. ⟨hal-03007828⟩

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Marie Vayer, Regis Guillot, Christophe Bour, Vincent Gandon. Revealing the Activity of π‐Acid Catalysts using a 7‐Alkynyl Cycloheptatriene. Chemistry – A European Journal, 2017, 23 (56), pp.13901-13905. ⟨10.1002/chem.201703817⟩. ⟨hal-05415407⟩

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Marie Vayer, Weizhen Fang, Régis Guillot, Sophie Bezzenine-Lafollée, Christophe Bour, et al.. Acid-catalysed intramolecular addition of β-ketoesters to 1,3-dienes. Organic & Biomolecular Chemistry, 2017, 15 (3), pp.584-588. ⟨10.1039/C6OB02122K⟩. ⟨hal-05415398⟩

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2016

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Bastien Michelet, Shun Tang, Guillaume Thiery, Julien Monot, Huijing Li, et al.. Catalytic applications of [IPr·GaX 2 ][SbF 6 ] and related species. Organic Chemistry Frontiers, 2016, 3 (12), pp.1603-1613. ⟨10.1039/C6QO00470A⟩. ⟨hal-03007837⟩

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Sara Morcillo, David Leboeuf, Christophe Bour, Vincent Gandon. Calcium‐Catalyzed Synthesis of Polysubstituted 2‐Alkenylfurans from β‐Keto Esters Tethered to Propargyl Alcohols. Chemistry – A European Journal, 2016, 22 (47), pp.16974-16978. ⟨10.1002/chem.201603929⟩. ⟨hal-05415396⟩

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Sara Morcillo, Marc Presset, Sébastien Floquet, Vincent Coeffard, Christine Greck, et al.. Site‐Selective Calcium‐Catalyzed/Organocatalyzed Condensation of Propargyl Alcohols Tethered to β‐Keto Esters. European Journal of Organic Chemistry, 2016, 2016 (15), pp.2688-2694. ⟨10.1002/ejoc.201600394⟩. ⟨hal-05415388⟩

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2015

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Christophe Bour, Régis Guillot, Vincent Gandon. First Evidence for the Existence of Hexafluoroantimonic(V) Acid. Chemistry – A European Journal, 2015, 21 (16), pp.6066-6069. ⟨10.1002/chem.201500334⟩. ⟨hal-01149540⟩

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Christophe Bour, Vincent Gandon. New Procedures for Catalytic Carbophilic Activation by Gold and Gallium π-Acids. SYNLETT, 2015, 26 (11), pp.1427-1436. ⟨10.1055/s-0034-1380712⟩. ⟨hal-01178959⟩

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Weizhen Fang, Marc Presset, Amandine Guérinot, Christophe Bour, Sophie Bezzenine, et al.. Copper(II) Triflate as Additive in Low Loading Au(I)-Catalyzed Hydroalkylation of Unactivated Alkenes. Organic Syntheses : An annual publication of satisfactory methods for the preparation of organic chemicals, 2015, 92, pp.117-130. ⟨10.15227/orgsyn.092.0117⟩. ⟨hal-05439398⟩

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David Lebœuf, Marc Presset, Bastien Michelet, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Ca II -Catalyzed Alkenylation of Alcohols with Vinylboronic Acids. Chemistry – A European Journal, 2015, 21 (31), pp.11001-11005. ⟨10.1002/chem.201501677⟩. ⟨hal-03007865⟩

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Bastien Michelet, Guillaume Thiery, Christophe Bour, Vincent Gandon. Non-Innocent Behavior of Substrate Backbone Esters in Metal-Catalyzed Carbocyclizations and Friedel–Crafts Reactions of Enynes and Arenynes. Journal of Organic Chemistry, 2015, 80 (21), pp.10925-10938. ⟨10.1021/acs.joc.5b02052⟩. ⟨hal-03007863⟩

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Bastien Michelet, Jean-Rémy Colard-Itté, Guillaume Thiery, Régis Guillot, Christophe Bour, et al.. Dibromoindium( iii ) cations as a π-Lewis acid: characterization of [IPr·InBr 2 ][SbF 6 ] and its catalytic activity towards alkynes and alkenes. Chemical Communications, 2015, 51 (34), pp.7401-7404. ⟨10.1039/C5CC00740B⟩. ⟨hal-03007870⟩

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Marc Presset, B. Michelet, Régis Guillot,, Christophe Bour, S. Bezzenine-Lafollée, et al.. Gallium(III)- and calcium(II)-catalyzed Meyer-Schuster rearrangements followed by intramolecular aldol condensation or endo-Michael addition. Chemical Communications, 2015, 51 (25), pp.5318-5321. ⟨10.1039/C4CC09514F⟩. ⟨hal-01159025⟩

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2014

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Christophe Bour, Vincent Gandon. Well-defined organo-gallium complexes as Lewis acids for molecular catalysis: Structure–stability–activity relationships. Coordination Chemistry Reviews, 2014, 279, pp.43-57. ⟨10.1016/j.ccr.2014.07.008⟩. ⟨hal-05439716⟩

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C. Bour, J. Monot, S. Tang, R. Guillot, Jonathan Farjon, et al.. Structure, stability, and catalytic activity of fluorine-bridged complexes IPr.GaCl2(µ-F)EFn-1 (EFn- = SbF6-, PF6-, or BF4-). Organometallics, 2014, 33 (2), pp.594-599. ⟨10.1021/om4012054⟩. ⟨hal-00953261⟩

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Weizhen Fang, Marc Presset, Amandine Guérinot, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Silver‐Free Two‐Component Approach in Gold Catalysis: Activation of [LAuCl] Complexes with Derivatives of Copper, Zinc, Indium, Bismuth, and Other Lewis Acids. Chemistry – A European Journal, 2014, 20 (18), pp.5439-5446. ⟨10.1002/chem.201304831⟩. ⟨hal-05415379⟩

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Weizhen Fang, Marc Presset, Amandine Guérinot, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Cationic gold(i)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity. Organic Chemistry Frontiers, 2014, 1 (6), pp.608. ⟨10.1039/C4QO00112E⟩. ⟨hal-05415380⟩

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Bastien Michelet, Christophe Bour, Vincent Gandon. Gallium-Assisted Transfer Hydrogenation of Alkenes. Chemistry – A European Journal, 2014, 20 (44), pp.14488-14492. ⟨10.1002/chem.201404139⟩. ⟨hal-03007877⟩

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2013

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Ahmad El-Hellani, Julien Monot, Shun Tang, Régis Guillot, Christophe Bour, et al.. Relationship between gallium pyramidalization in L*GaCl3 complexes and the electronic ligand properties.. Inorganic Chemistry, 2013, 52 (19), pp.11493-11502. ⟨10.1021/ic401817g⟩. ⟨hal-00933544⟩

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Amandine Guérinot, Weizhen Fang, Marie Sircoglou, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Copper Salts as Additives in Gold(I)‐Catalyzed Reactions. Angewandte Chemie International Edition, 2013, 52 (22), pp.5848-5852. ⟨10.1002/anie.201300600⟩. ⟨hal-05415377⟩

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2012

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Ahmad El-Hellani, Julien Monot, Régis Guillot, Christophe Bour, Vincent Gandon. Molecular versus Ionic Structures in Adducts of GaX 3 with Monodentate Carbon-Based Ligands. Inorganic Chemistry, 2012, 52 (1), pp.506-514. ⟨10.1021/ic302440g⟩. ⟨hal-05415375⟩

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Shun Tang, Julien Monot, Ahmad El-Hellani, Bastien Michelet, Régis Guillot, et al.. Cationic Gallium(III) Halide Complexes: A New Generation of π-Lewis Acids. Chemistry – A European Journal, 2012, 18 (33), pp.10239-10243. ⟨10.1002/chem.201201202⟩. ⟨hal-03007906⟩

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2011

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Ahmad El-Hellani, Christophe Bour, Vincent Gandon. Evaluation of the Electronic Properties of a Carbodiphosphorane through Gold Catalysis. Advanced Synthesis and Catalysis, 2011, 353 (11-12), pp.1865-1870. ⟨10.1002/adsc.201100287⟩. ⟨hal-05415366⟩

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Don Antoine Lanfranchi, Christophe Bour, Gilles Hanquet. Enantioselective Access to Key Intermediates for Salvinorin A and Analogues. European Journal of Organic Chemistry, 2011, 2011 (15), pp.2818-2826. ⟨10.1002/ejoc.201100207⟩. ⟨hal-05017242⟩

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2008

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Gaëlle Specht-Blond, Christophe Bour, Bahaâ Salem, Jean Suffert. A New Pd-Catalyzed Cascade Reaction for the Synthesis of Strained Aromatic Polycycles. Organic Letters, 2008, 10 (6), pp.1075-1078. ⟨10.1021/ol702855h⟩. ⟨hal-04563621⟩

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2006

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C. Bour, J. Suffert. 4-Exo-dig Cyclocarbopalladation: A Straightforward Synthesis of Cyclobutane diols from Acyclic Γ-Bromopropargylicdiols under Microwaves Irradiation. Journal of Organic Chemistry, 2006, pp.1391. ⟨hal-00142895⟩

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Christophe Bour, Gaëlle Blond, Bahaâ Salem, Jean Suffert. 4-exo-dig and 5-exo-dig Cyclocarbopalladations: an expeditious solution toward molecular complexity?. Tetrahedron, 2006, 62 (45), pp.10567-10581. ⟨10.1016/j.tet.2006.06.116⟩. ⟨hal-04819282⟩

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C. Bour, J. Suffert. 4-Exo-dig Cyclocarbopalladation: A Straightforward Synthesis of Cyclobutane diols from Acyclic ?-Bromopropargylicdiols under Microwaves Irradiation. European Journal of Organic Chemistry, 2006, pp.1391-1393. ⟨hal-00129819⟩

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C. Bour, G. Blond, B. Salem, J. Suffert. 4-exo-dig and 5-exo-dig Cyclocarbopalladation: an Expeditious Solution toward Molecular Complexity?. Tetrahedron, 2006, 62, pp.10567-10581. ⟨hal-00142922⟩

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2005

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C. Bour, J. Suffert. Cyclocarbopalladation: Sequential Cyclization and CH Activation/Sqtille Cross-Coupling in the Pd-5-Exo-Dig Reaction. Org. Letters, 2005, 7, pp.653-655. ⟨hal-00129818⟩

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A. Mota, A. Dedieu, C. Bour, J. Suffert. Cyclocarbopalladation Reactions Involving an Unusual 1,5-Palladium Vinyl to Aryl Shift as Termination Step: Theoretical Study of the Mechanism.. Journal of the American Chemical Society, 2005, 127, pp.7171. ⟨hal-00129940⟩

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Conference papers

2024

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Christophe Bour. HFIP in Homogeneous Catalysis. Fostering Sustainable Catalysis 2024, Jan 2024, Delhi (India), India. ⟨hal-04595501⟩

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Book sections

2018

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Loic Pantaine, Christophe Bour, Géraldine Masson. Photo-induced multi-component reactions. Photochemistry: Volume 46, pp.395-431, 2018, ⟨10.1039/9781788013598-00395⟩. ⟨hal-02324699⟩

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2014

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Masahiko Yamaguchi, Shigeki Matsunaga, Masakatsu Shibasaki, Bastien Michelet, Christophe Bour, et al.. Gallium Trichloride. Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, Ltd, 2014, ⟨10.1002/047084289X.rn00118u.pub3⟩. ⟨hal-03007900⟩

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Other publications

2018

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Mouhamad Awada, Sebastien Floquet, Mohamed Haouas, Nancy Watfa, Jerome Marrot, et al.. Functionalization of Mo132 Keplerate Nanocapsules by Cyclic Carboxylates: L-proline vs Cyclopentanecarboxylate. 2018, pp.39-47. ⟨10.2174/1877944107666171102123712⟩. ⟨hal-04418263⟩

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Patents

2019

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Christophe Bour, Marie Vayer, Vincent Gandon. New method for the synthesis of unsymmetrical tertiary amines by iron-catalyzed reductive alkylation of imines with alcohols, preferably ethanol. France, Patent n° : WO 2019063952 A1 20190404. 2019. ⟨hal-05440069⟩

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